Is Hydrogen Bonding the Sole Factor Affecting Viscosity and Surface Tension?

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SUMMARY

This discussion centers on the relationship between hydrogen bonding, viscosity, and surface tension, specifically comparing water and glycerol. The findings indicate that while water exhibits higher surface tension than glycerol, glycerol is more viscous. The common belief that viscosity and surface tension are solely dependent on hydrogen bonding is challenged, as other factors also play significant roles. The example of polyethylene, which lacks hydrogen bonding yet has high viscosity, further supports this conclusion.

PREREQUISITES
  • Understanding of hydrogen bonding in molecular chemistry
  • Knowledge of viscosity and surface tension concepts
  • Familiarity with the properties of water and glycerol
  • Basic principles of fluid dynamics
NEXT STEPS
  • Research the molecular structure of glycerol and its impact on viscosity
  • Explore the effects of temperature on viscosity and surface tension
  • Investigate the role of intermolecular forces beyond hydrogen bonding
  • Learn about the viscosity of non-polar substances like polyethylene
USEFUL FOR

Chemistry students, physicists, and researchers interested in fluid dynamics and intermolecular forces will benefit from this discussion.

Kracatoan
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Just given in my physics Coursework and I wanted to see what you lot thought about my rather interesting results.

Basically, I compared the vicosity and surface tension of both water and glycerol through a series of tests and was rather surprised at what I found. According to my results (and data books when I checked), water has a higher surface tension than glycerol, but glycerol is more viscous than water.

Everything I have read on the internet and heard from Chemistry teachers is that both viscosity and surface tension are directly proportional to the amount of hydrogen bonds a molecule has, but obviously that cannot be the whole truth.

Any thoughts on this?
 
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Kracatoan said:
Everything I have read on the internet and heard from Chemistry teachers is that both viscosity and surface tension are directly proportional to the amount of hydrogen bonds a molecule has, but obviously that cannot be the whole truth.

In short - all other things being equal the more hydrogen bonds, the higher the surface tension and viscosity. But obviously water and glycerol are too different for such a simple rule to be effective.
 
Polyethylene has almost no hydrogen bonding but is so much thicker than both.
 

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