Is the molecular formula for sugar correct?

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SUMMARY

The molecular formula for sugar, specifically saccharose, is definitively C12H22O11, following the Hill system convention which orders elements as Carbon (C), Hydrogen (H), and then alphabetically. Alternative representations such as H22C12O11 or O11C12H22 are incorrect as they do not adhere to established naming conventions. Similarly, sulfuric acid is correctly represented as H2SO4, with the hydrogen ions placed first due to its classification as an inorganic acid. The discussion highlights the importance of following systematic naming conventions in chemistry.

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akerkarprashant
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TL;DR
Molecular formula correction.
Is the following molecular formula for Sugar can be written as
H22C12O11 or
O11C12H22 or
O11H22C12 or
C12O11H22 or
H22O11C12
instead of C12H22O11?

Logically they can be written as mentioned above?

If Not, Why?

There can be many more examples similar to above.
 

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Thanks.

Another example could be for Sulphuric acid having molecular formula as H2SO4.

This can be SH2O4,O4H2S,H2O4S, SO4H2,O4SH2.

Thanks & Regards,
Prashant S Akerkar
 
Two totally different cases.

The molecular formula for saccharose is C12H22O11 in that order -- by convention: Alphabetical. Doesn't tell you all you need to know to reconstruct the molecule. For that the IUPAC name (horrible ! See 3.1.1 here) is intended.

Sulfuric acid contains a functional group SO42- and -- as an inorganic acid -- its name by convention starts with the hydrogen ions. Hence H2SO4

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Thanks.

Mostly the convention for Molecular formulas will be alphabetical based ?

Is there a good site which sets the rules for molecular formula naming conventions?

Thanks & Regards,
Prashant S Akerkar
 
Not really. You could try Googling 'Hill system' or 'Richter system formulas'. Or even simply 'Chemical formula'

And my 'alphabetical' appears to be too simple-minded. The Hill system has C, H and then alphabetical, the RIchter system is still quite relevant (e.g. for Beilstein !). See e.g. here

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Wait, so what about NH3?
 
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IUPAC colored books (never remember which one is which) are definitive source for conventions used. In some cases general convention says one thing, but common, well established names/formulas are allowed.

That's mostly for historical reasons, way too many names and conventions are well established, universally understood, but unsystematic.
 
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Here is one uncalled for, unprofessional opinion.

We usually put cations to the left and anions to the right (NaCl, K2S, etc.). This goes for covalent compounds, too, where we use oxidation numbers (SO2, H2S, etc). Exception ammonia, probably for historical reasons.
 

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