Is the Radial Wave Function R_{31} Normalized Correctly?

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SUMMARY

The discussion focuses on the normalization of the radial wave function R_{31} for the hydrogen atom, specifically the expression \(\frac{1}{a_{0}^{3/2}}\frac{4}{81\sqrt{6}}\left(6-\frac{r}{a_{0}}\right)\frac{r}{a_{0}}e^{-r/3a_{0}}\). Participants analyze the integral \(\int^{\infty}_{0}r^{2}R_{31}*R_{31}dr=1\) and identify issues with constants and terms in their calculations. The consensus is that the integration must account for spherical coordinates, leading to the correct formulation of the integral as \(\int_0^\infty (u^6 - 12u^5 + 36u^4)e^{-2u/3} du\). A key integral for solving this is \(\int^{\infty}_{0}x^n e^{-ax}dx=\frac{n!}{a^{n+1}}\).

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Homework Statement


Show that the radial function R_{31} is normalized.

Homework Equations


\frac{1}{a_{0}^{3/2}}\frac{4}{81\sqrt{6}}\left(6-\frac{r}{a_{0}}\right)\frac{r}{a_{0}}e^{-r/3a_{0}}

\int^{\infty}_{0}r^{2}R_{31}*R_{31}dr=1

The Attempt at a Solution


So I plugged that radial function in and got \int^{\infty}_{0}a_{0}^{2}u^{2}\left(6u-u^{2}\right)^{2}e^{-2u/3}du=1 all multiplied by some constant and u=\frac{r}{a_{0}}

I'm getting \frac{243}{4} times the constant, and that does not equal one. So I feel like I'm not using the right equation for this one.
 
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Remember what coordinate system you are working in.
 
Spherical coordinates. So there's an r^2 thrown in there. Did I not account for everything in my integral?
 
Well, it looks like you didn't in your equation with the u's.
 
I'm seeing an extra a_o^2, since there's an (\frac{1}{a_0^{3/2}})^2 = \frac{1}{a_0^3} term, an r^2 = a_0^2u^2 term, and a dr = a_0 du term:

\frac{1}{a_0^3}a_0^2u^2a_0 du = u^2 du

I'm curious as to how you're going about integrating

C\int_0^\infty (u^6 - 12u^5 + 36u^4)e^{-2u/3} du ?

Does this have to be done by repeated parts (after you split it up of course), or is there a trick?
 
dotman said:
I'm curious as to how you're going about integrating

C\int_0^\infty (u^6 - 12u^5 + 36u^4)e^{-2u/3} du ?

Does this have to be done by repeated parts (after you split it up of course), or is there a trick?

A very useful definite integral that was given to me when I learned about the hydrogen atom is

\int^{\infty}_{0}x^n \; e^{-ax}dx=\frac{n!}{a^{n+1}}; \; (a>0;\; n\; integer \:>0)
 

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