Modeling CO2 Laser as a 4-Level Laser

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SUMMARY

The discussion clarifies that a CO2 laser can indeed be modeled as a four-level laser system, despite differences in radiative transitions compared to a generic four-level laser. In the CO2 laser, the transitions occur between vibrational modes: specifically, from the anti-symmetric vibrational mode (v3) to the symmetric vibrational mode (v1), with energy released as a photon. The conversation emphasizes that while the radiative transitions differ, both systems contain four energy levels, fulfilling the criteria for a four-level laser model.

PREREQUISITES
  • Understanding of laser fundamentals as outlined in Svelto's "Principles of Lasers"
  • Familiarity with vibrational modes in molecular systems
  • Knowledge of rate equations in laser physics
  • Basic principles of energy transitions and conservation laws
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  • Study the vibrational modes of CO2 molecules in detail
  • Research the differences between four-level and three-level laser systems
  • Explore the role of collisions in gas lasers and their impact on transitions
  • Examine rate equations specific to CO2 laser operation
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Physics students, laser technology researchers, and engineers interested in laser design and operation, particularly those focusing on CO2 laser systems.

chimay
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I am not sure this is the right place where I should post, I hope I've chosen the right section.

I'm studying laser's fundamentals on Svelto's "Principles of Lasers". Here I find the description of a generic four level laser by means of rate equations; it can be represented like this: (first picture)

Then, I read that the CO2 laser, whose basic scheme is in the second picture, can be modeled as a four-levele laser too; I don't understand why this is true. In the CO2 laser the radiative transition is between level 3 and 2, while in the first photo it is between 2 and 1. Moreover, level n.3 in the first picture should be pratically empty, while in the CO2 laser it isn't so.

Can anyone explain me how I can model a CO2 laser like a four-level laser like the one in the first picture?

Thanks.
 

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I am not a laser expert, but maybe this helps. The pictures are describing somewhat different processes. The CO2 laser is a four level system:

v0: ground state
v1: symmetric vibrational mode
v2: bending mode
v3: anti-symmetric vibrational mode

In the CO2 laser you have a lasing from the anti-symmetric (v3) vibrational mode to the symmetric vibrational (v1) mode with the release of energy as a photon. Such a transistion satisfies conservation laws. However, you can also have relaxations between the antisymmetric mode (v3) and the "bending mode" (v2), yet this is not an optically active transition. The v3-v2 transitions are due to collisions in the gas.

the first picture (left) also shows a four level system with lasing between levels (v2) and (v1). A system like this would have a molecule excited to (v3). The molecule then relaxes to (v2) and lases from (v2 to v1). Finally the molecule may relaxes from v1 to the ground state v0 via collisions.
 
So your point is "there are 4 levels in both cases, they just differ from the radiative transition, 3->2 instead of 2->1", is it?
 
Yes - I think that is what is going on
 

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