Naoh in sodium acetate, raise pH

  • Thread starter Thread starter Puchinita5
  • Start date Start date
  • Tags Tags
    Ph Sodium
Click For Summary
SUMMARY

The discussion revolves around calculating the volume of 10N NaOH required to raise the pH of a 0.1L solution of 1M sodium acetate from 5.5 to 6.0. The participant correctly identifies that the solution acts as a buffer due to the presence of acetic acid, calculating that 0.01177 moles of NaOH is needed. This translates to approximately 1.2 mL of 10N NaOH when considering significant figures. The calculations are confirmed to be logically sound, although the participant expresses uncertainty about the accuracy of their numbers.

PREREQUISITES
  • Understanding of buffer solutions and their pH calculations
  • Knowledge of the Henderson-Hasselbalch equation
  • Familiarity with molarity and volume conversions
  • Basic chemistry knowledge regarding strong bases like NaOH
NEXT STEPS
  • Study the Henderson-Hasselbalch equation in detail
  • Learn about buffer capacity and its implications in pH adjustments
  • Explore titration techniques for precise pH adjustments
  • Investigate the effects of strong bases on weak acid solutions
USEFUL FOR

Chemistry students, laboratory technicians, and anyone involved in pH adjustment and buffer solution preparation will benefit from this discussion.

Puchinita5
Messages
178
Reaction score
0
I need someone to tell me if I did this right...

What volume of 10N NaOH should be added to 0.1L of 1 M sodium acetate pH 5.5 to change the pH to 6.0.

so I'm assuming that there is also an amount of acetic acid in this solution for it to have an acidic pH right? So is it a buffer?

In which case,

5.5 = 4.76 + log (1M NaOac / x M Oac)

and so x is 0.182 M acetic acid. or .0182 moles

to raise the ph to 6

i'm assuming it will take away a certain amount from acetic acid and add a certain amount to sodium acetate...so...

6 = 4.76 + log( 0.1 + x / 0.0182 - x)

and solving for x gives me 0.01177 moles of NaOH which is 0.001 Liters of 10 M NaOH.These numbers look awful to me so I feel like I did this wrong. Is this right?
 
Physics news on Phys.org
NaOH is very strong base and only few drops can make the solution basic, so I don't think the answer might be wrong. Better if I try it myself.
 
Logic is correct. I have not checked the numbers, but they don't look absurd to me. Just note you have to give higher accuracy - 0.01177 moles is not 0.001 L. More like 1.177 mL or rather 1.2 mL (0.0012 L) to keep the reasonable number of significant digits.
 

Similar threads

  • · Replies 7 ·
Replies
7
Views
2K
  • · Replies 3 ·
Replies
3
Views
3K
  • · Replies 2 ·
Replies
2
Views
3K
  • · Replies 8 ·
Replies
8
Views
2K
  • · Replies 11 ·
Replies
11
Views
3K
Replies
4
Views
4K
  • · Replies 7 ·
Replies
7
Views
4K
  • · Replies 1 ·
Replies
1
Views
2K
  • · Replies 1 ·
Replies
1
Views
3K
  • · Replies 20 ·
Replies
20
Views
3K