No vibration spectrum for homonuclear diatomic molecules?

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SUMMARY

Homonuclear diatomic molecules, such as O2 and N2, do not exhibit vibrational spectra due to their zero dipole moment. According to established principles, a diatomic molecule must have a dipole moment that varies with molecular extension to produce a vibrational spectrum. Since homonuclear diatomic molecules maintain symmetry, their dipole moment remains zero regardless of extension, preventing electric-dipole vibrational transitions.

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bahamagreen
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Supposed to be because they have a zero dipole moment...

Dipole moment is variously described using neutral systems of pairs of opposite charge, or single items with charge, but I am finding no explanations of same charge pairs I understand..

Wiki states: "To show a vibrational spectrum, a diatomic molecule must have a dipole moment that varies with extension. So, homonuclear diatomic molecules do not undergo electric-dipole vibrational transitions. So, a homonuclear diatomic molecule doesn't show purely vibrational spectra."

How does the dipole moment not vary with extension?
 
Physics news on Phys.org
In a homonuclear diatomic molecule there is no dipole moment because of the additional symmetry. Therefore, the dipole moment is zero regardless of extension and thus independent of the extension.
 

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