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We know that the Pauli matrices along with the identity form a basis of 2x2 matrices. Any 2x2 matrix can be expressed as a linear combination of these four matrices. I know of one proof where I take

[itex] a_{0}\sigma_{0}+a_{1}\sigma_{1}+a_{2}\sigma_{2}+a_{3}\sigma_{3}=0[/itex]

Here, [itex]\sigma_{0}[/itex] is the identity. We get four simultaneous equations in [itex] a_{i}[/itex] and it is fairly trivial to show that each [itex] a_{i}[/itex] must be zero. This implies that the four matrices are linearly independent and therefore form a basis for 2x2 matrices.

But I recently discovered a different way to show this. This utilizes a matrix inner product defined by [itex]\sigma_{i}.\sigma_{j} = \frac{1}{2}Tr(\sigma_i \sigma_{j}^{\bot})[/itex]. Here [itex]A^{\bot}[/itex] is the transpose conjugate and the 1/2 is just to remove the factor of 2 that arises from the matrices being 2x2. The argument goes that this definition gives the inner product equal to 1 if i=j and 0 otherwise meaning that the four matrices we have are orthogonal. Since there are four of them, and the orthogonality is interpreted as linear independence, they form a basis.

My question is, how can I connect these two proofs? The second one seems nice but I cannot see how it is the same, in general, as the first proof. The definition of orthogonality seems arbitrary (it obeys the axioms for inner product, yes, but surely there is more than that) and I cannot really see how showing that matrices that are orthogonal by this definition makes them linearly independent in the way the first proof shows. Thank you very much for your help.