Perturbation Theory - expressing the perturbation

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SUMMARY

The discussion focuses on the perturbation theory applied to the Coulomb potential energy in a hydrogen atom. The user presents a mutual Coulomb potential defined by two cases: one for \(0 < r \leq b\) and another for \(r > b\). The total perturbation is expressed as \(\delta\hat H = - \frac{e^{2}}{4\pi\epsilon_{0}}(\frac{b}{r^{2}} + \frac{1}{r})\). However, a critical correction is noted, indicating that the Coulomb potential should be subtracted in the perturbation expression.

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Zero1010
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Homework Statement
Specify the perturbation for the Coulomb model of hydrogen.
Relevant Equations
##V(x) =

\begin{cases}

-\frac{e^{2}}{4\pi\epsilon_{0}}\frac{b}{r^{2}} \text{if } 0<r \leq 0 \\

-\frac{e^{2}}{4\pi\epsilon_{0}}\frac{1}{r} \text{if } r > 0

\end{cases} ##
Hi,

I just need someone to check if I am on the right track here

Below is a mutual Coulomb potential energy between the electron and proton in a hydrogen atom which is the perturbed system:

##V(x) =
\begin{cases}
- \frac{e^{2}}{4\pi\epsilon_{0}}\frac{b}{r^{2}} \text{for } 0<r \leq 0 \\
- \frac{e^{2}}{4\pi\epsilon_{0}}\frac{1}{r} \text{for } r > 0
\end{cases} ##

Where e = mag of electron charge, B = a constant length, ##4\pi\epsilon_{0}## = permittivity of free space

Using this I need to specify the perturbation of the system.

Since V(x) is the perturbed system is the total perturbation the sum of both these functions across the length?

In which case I get:

##\delta\hat H = - \frac{e^{2}}{4\pi\epsilon_{0}}\frac{b}{r^{2}} + (- \frac{e^{2}}{4\pi\epsilon_{0}}\frac{1}{r})##

##\delta\hat H = - \frac{e^{2}}{4\pi\epsilon_{0}}(\frac{b}{r^{2}} + \frac{1}{r})##

I just want to check if this is the correct way to go about this?

Thanks in advance.
 
Last edited:
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I don't understand the potential you are looking at. Usually for the hydrogen atom you just use the simple Coulomb potential. What does the first line mean? ##0<r \leq 0## is self-contradictory, because ##r>0## already implies that ##r \neq 0##.
 
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Thanks for the reply.

Sorry that's my typo it should be:

##0 \lt r \leq b##

and the second one should be

##r \gt b##

Also in the question it says to suppose there is a deviation from Coulombs law at very small distances (even though there is no evidence for it)
 
Zero1010 said:
Homework Statement:: Specify the perturbation for the Coulomb model of hydrogen.
Relevant Equations:: ##V(x) =

\begin{cases}

-\frac{e^{2}}{4\pi\epsilon_{0}}\frac{b}{r^{2}} \text{if } 0<r \leq 0 \\

-\frac{e^{2}}{4\pi\epsilon_{0}}\frac{1}{r} \text{if } r > 0

\end{cases} ##

Hi,

I just need someone to check if I am on the right track here

Below is a mutual Coulomb potential energy between the electron and proton in a hydrogen atom which is the perturbed system:

##V(x) =
\begin{cases}
- \frac{e^{2}}{4\pi\epsilon_{0}}\frac{b}{r^{2}} \text{for } 0<r \leq 0 \\
- \frac{e^{2}}{4\pi\epsilon_{0}}\frac{1}{r} \text{for } r > 0
\end{cases} ##

Where e = mag of electron charge, B = a constant length, ##4\pi\epsilon_{0}## = permittivity of free space

Using this I need to specify the perturbation of the system.

Since V(x) is the perturbed system is the total perturbation the sum of both these functions across the length?

In which case I get:

##\delta\hat H = - \frac{e^{2}}{4\pi\epsilon_{0}}\frac{b}{r^{2}} + (- \frac{e^{2}}{4\pi\epsilon_{0}}\frac{1}{r})##

##\delta\hat H = - \frac{e^{2}}{4\pi\epsilon_{0}}(\frac{b}{r^{2}} + \frac{1}{r})##

I just want to check if this is the correct way to go about this?

Thanks in advance.
You should be subtracting the Coulomb potential in ##\delta\hat H##.
 
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