Product at anode of the electrolysis of MgBr2

[Janiceleong26]

1. Homework Statement

Why is the product at anode Br2 for MgBr2? Instead of O2?

Homework Equations

The Attempt at a Solution

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The E^Θ value for the oxidation of OH^- is -0.40 V,
And that of Br^- is -1.07V
And so, shouldn't oxidation of OH^- be easier? And hence, O2 is formed at the anode?

 

[Borek]

If memory serves me well, the explanation lies in the kinetics. In general yes, oxygen should be formed. In practice oxygen evolution is quite slow, so you need an overpotential to speed it up, which moves you into the voltages where Br₂ is produced. It is the same with brine solutions, where you can easily smell chlorine despite the fact oxygen should evolve first.

 

[Janiceleong26]

If memory serves me well, the explanation lies in the kinetics. In general yes, oxygen should be formed. In practice oxygen evolution is quite slow, so you need an overpotential to speed it up, which moves you into the voltages where Br₂ is produced. It is the same with brine solutions, where you can easily smell chlorine despite the fact oxygen should evolve first.

Woah I see.. How am suppose to know this during the exam ?
Anyways, thanks. Are there any other exceptions other than brine and MgBr2?

 

[Borek]

I believe oxygen in general evolves slowly, so whenever it is one of possible products, other things can be produced as well at higher potentials.

Note: I am not entirely sure about this explanation, take it with a grain of salt.

 

[Janiceleong26]

I believe oxygen in general evolves slowly, so whenever it is one of possible products, other things can be produced as well at higher potentials.

Note: I am not entirely sure about this explanation, take it with a grain of salt.

Alright, thanks!

 

[Abdullah Zeeshan]

If memory serves me well, the explanation lies in the kinetics. In general yes, oxygen should be formed. In practice oxygen evolution is quite slow, so you need an overpotential to speed it up, which moves you into the voltages where Br₂ is produced. It is the same with brine solutions, where you can easily smell chlorine despite the fact oxygen should evolve first.

Thank you borek

 

[Abdullah Zeeshan]

If memory serves me well, the explanation lies in the kinetics. In general yes, oxygen should be formed. In practice oxygen evolution is quite slow, so you need an overpotential to speed it up, which moves you into the voltages where Br₂ is produced. It is the same with brine solutions, where you can easily smell chlorine despite the fact oxygen should evolve first.

Thank you borek