Propagators for time-dependent Hamiltonians

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SUMMARY

The discussion centers on the propagators for time-dependent Hamiltonians in quantum mechanics, specifically addressing the time-dependent Schrödinger equation. The solution to this equation involves the time-evolution operator, defined as hat{C}(t,t_0)=\mathcal{T}_c \exp[-\mathrm{i} \int_{t_0}^t \mathrm{d} t' \hat{H}(t)], which incorporates time-ordering through the operator \mathcal{T}_c. The propagator is expressed as U(t,\vec{x};t_0,\vec{x}')=\langle \vec{x}|\hat{C}(t,t_0)|\vec{x}' \rangle, allowing for the computation of solutions to the time-dependent Schrödinger equation via integration over initial conditions.

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  • Understanding of the time-dependent Schrödinger equation
  • Familiarity with quantum mechanics concepts such as Hamiltonians and wave functions
  • Knowledge of time-ordering operators in quantum field theory
  • Experience with mathematical techniques for power series expansions
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  • Study the derivation and applications of the time-evolution operator \hat{C}(t,t_0)
  • Explore the implications of time-dependent Hamiltonians on quantum state evolution
  • Learn about the mathematical formulation of time-ordering in quantum mechanics
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Quantum physicists, graduate students in physics, and researchers focusing on time-dependent systems in quantum mechanics will benefit from this discussion.

AxiomOfChoice
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Suppose I know

[tex] H \psi(x) = \left( -\frac{1}{2m} \Delta_x + V(x) \right) \psi(x) = E\psi(x).[/tex]

Then

[tex] \psi(x,t) = e^{-iEt}\psi(x)[/tex]

solves the time-dependent Schrödinger equation

[tex] \left( i \frac{\partial}{\partial t} + \frac{1}{2m} \Delta_x - V(x) \right)\psi(x,t) = 0.[/tex]

I've done some computations, and it looks like

[tex] \Psi(x,t) = e^{-imvx}e^{-imv^2t/2}\psi(x+vt)[/tex]

is a solution to the time-dependent Schrödinger equation

[tex] \left( i \frac{\partial}{\partial t} + \frac{1}{2m} \Delta_x - V(x+vt) \right)\Psi = 0.[/tex]

I have a couple of questions about this:
  1. What is going on here physically? That is, what are those two phase factors telling me?
  2. What does this mean the propagator is? When [itex]H[/itex] is time-independent, [itex]U(t) = e^{-iEt}[/itex]...but what is it in the time-dependent case? Is there a neat little formulation of it?
 
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With the ansatz
[tex]\psi(t,\vec{x})=\exp(-\mathrm{i} E t) \phi_{E,\alpha}(\vec{x}),[/tex]
you only get the energy-eigensolutions (stationary states) for a time-independent Hamiltonian,
[tex]\hat{H} \phi_{E,\alpha}(\vec{x})=E \phi_{E,\alpha}(\vec{x}).[/tex]
Here [itex]\alpha[/itex] stands for all necessary additional observables, compatible with energy, to label the possible degeneracy of the energy eigenstates.

The most general solution of the time-dependent Schrödinger equation is then given as a superposition of energy eigensolutions
[tex]\psi(t,\vec{x})=\sum_{E,\alpha} \exp(-\mathrm{i} E t) \phi_{E,\alpha}(\vec{x}).[/tex]

This is all for time-independent Hamiltonians. For time-dependent Hamiltonians, the problem is a bit more complicated. Here you get a formal solution by using the time-evolution operator for the state in the Schrödinger picture,
[tex]\hat{C}(t,t_0)=\mathcal{T}_c \exp[-\mathrm{i} \int_{t_0}^t \mathrm{d} t' \hat{H}(t)],[/tex]
where [itex]\mathcal{T}_c[/itex] is the time-ordering operator that orders products of time-dependent operators such that the time arguments are ordered from right to left.

The exponential must be formaly expanded in terms of a power series to make sense of this time-ordering symbol. The nth-order contribution is
[tex]\hat{C}_n(t,t_0)=\frac{(-\mathrm{i})^n}{n!} \int_{t_0}^t \mathrm{d} t_1 \cdots \int_{t_0}^t \mathrm{d} t_n \mathcal{T}_c \hat{H}(t_1) \cdots \hat{H}(t_n).[/tex]
Then
[tex]\hat{C}(t,t_0)=\sum_{n=0}^{\infty} \hat{C}_n(t,t_0).[/tex]

The propagator of the Schrödinger equation is then given by
[tex]U(t,\vec{x};t_0,\vec{x}')=\langle \vec{x}|\hat{C}(t,t_0)|\vec{x}' \rangle,[/tex]
and the solution of the time-dependent Schrödinger equation reads
[tex]\psi(t,\vec{x})=\int_{\mathbb{R}^3} \mathrm{d}^3 \vec{x'} U(t,\vec{x};t_0,\vec{x}') \psi(t_0,\vec{x}').[/tex]
 

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