Question about balancing a reaction

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SUMMARY

The reaction H3PO4(aq) + KMnO4(aq) + H2SO4(aq) → H3PO4(aq) + MnSO4(aq) + K2SO4(aq) + H2O(l) cannot be balanced due to the presence of the same compound, H3PO4, on both sides, which complicates the balancing process. The reaction involves five elements: K, Mn, H, S, and O, but only four degrees of freedom are available for balancing, leading to an unsolvable equation. The permanganate ion (MnO4-) is not oxidizing anything in this reaction, confirming that it does not represent a valid redox process.

PREREQUISITES
  • Understanding of redox reactions and oxidation states
  • Familiarity with balancing chemical equations
  • Knowledge of the properties of permanganate ions (KMnO4)
  • Basic concepts of stoichiometry in chemical reactions
NEXT STEPS
  • Study the principles of balancing redox reactions in acidic solutions
  • Learn about the role of permanganate as an oxidizing agent in various reactions
  • Explore the concept of degrees of freedom in chemical equations
  • Review examples of reactions that include the same compound as both a reactant and a product
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Chemistry students, educators, and anyone interested in mastering chemical reaction balancing and redox processes.

yuval12
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Homework Statement
balancing a reaction
Relevant Equations
H3PO4(aq) + KMnO4(aq) + H2SO4(aq) → H3PO4(aq) + MnSO4(aq) + K2SO4(aq) + H2O(l)
hi,

I was asked to balance this reaction :

H3PO4(aq) + KMnO4(aq) + H2SO4(aq) → H3PO4(aq) + MnSO4(aq) + K2SO4(aq) + H2O(l)

can I get some help? why we can't balance this reaction? and what can we say about a reaction that has the same compound as a reagent and a product?
thank you
 
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That's not a reaction. Mn is being reduced, but nothing is being oxidised. Have you copied it correctly?
 
yes, our teacher insists that there is no mistake in the reaction
 
I assure you there is. What is the permanganate oxidising?
 
You were told exactly the same at other forum, weren't you?
 
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yuval12 said:
Relevant Equations:: H3PO4(aq) + KMnO4(aq) + H2SO4(aq) → H3PO4(aq) + MnSO4(aq) + K2SO4(aq) + H2O(l)

why we can't balance this reaction?
Ignoring H3PO4(aq) which needs to stay balanced (only chemical with P) you have five elements, K, Mn, H, S, O, that have to match on both sides -> 5 equations. You have five chemicals there, which gives you four degrees of freedom to try to balance the equation (the fifth is just an overall scaling of the reaction). There is no solution to that problem here. It's like trying to solve "x=5 and x=7". Find x such that both equations are satisfied. You can't.
 

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