Radioactive Dating: Calculating Half-Life & Remaining Mass

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SUMMARY

The discussion centers on calculating the remaining mass of lead-210 (Pb-210) after a specified time using the formula N = N0 e^(-kT), where N0 is the initial mass, T is time, and k is the decay constant derived from the half-life (T1/2 = 22.3 years). The initial mass of Pb-210 is 7.5 grams, and after 17.5 years, the calculation yields 4.36 grams remaining. The confusion arises regarding the conversion to mercury-206 (Hg-206), with participants debating the correct interpretation of the decay process and the impact of alpha decay on mass. The correct remaining mass of Hg-206 should be approximately 3.09 grams, factoring in the decay process and mass loss.

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Homework Statement



chemproblem.png

Homework Equations


N= (N_0) e^(-kT)
k = ln(2)/(T_1/2)

The Attempt at a Solution


N0 = 7.5g
T_1/2 = 22.3 years
T = 17.5 years

k = ln(2)/22.3 = .031

N = 7.5 e^(-.031 * 17.5)
N = 4.36 g

So I chose A, but the correct answer was B. can't figure out where I went wrong
 
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You calculated the amount of Pb210 after 17.5a, you were asked for the amount of Hg206
 
then wouldn't it be 7.5 - 4.36 = 3.14? because you start with 7.5 and end up with 4.36 and the rest was converted to Hg206. I am still doing something wrong though because I am supposed to end up with 3.09
 
Do you think that after 22.5years, 7.5g of Pb will become 3.75g of Pb and 3.75g of Hg?
Does Hg have the same density as Pb?
 
Pb is slightly more dense. I'm not sure how to include this in the calculation though. if at the beginning all 7.5 grams is Pb and after the time has elapsed 4.36 of the 7.5 is Pb then I have a hard time understanding how Hg won't be the remainder of the 7.5 grams
 
What is the decay mode?
 
i am pretty sure it undergoes alpha decay
 
I would look for atomic numbers of isotopes mentioned.

But in general, if it is alpha decay, you can assume mass of the nucleus changes by 4.
 
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Bit of a trick question IMHO. Firstly you misread it, but I'd call that a set trap.:devil: Then you made your calculation and, once you realize the first trap the result is clearly nearer one figure, D, than another one. But the second trap :devil: is there is a 2% difference due to the mass change (which was given in the problem).

It would be fair to ask questions as a quiz when it is possible to get answers by principles or ballpark reasoning. It would be fair to ask the question with no answers given, since you can eliminate some answers by ballpark, but you cannot choose between B and D without calculation. But they have set you up by two answers meant to confirm you in mistakes!

These people are evil. :devil: :devil:
 
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yeah i like better when tests are not multiple choice and have partial credit. That way they can grade you on your method of solving instead of just running it through a scantron =\

so the reason its B) is because of the mass that becomes the alpha particle?
 

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