Rates of Reaction: Calcium Carbonate & 0.1 M Acids

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SUMMARY

The reaction rate of calcium carbonate with 0.1 M hydrochloric acid is significantly faster than with 0.1 M ethanoic acid due to the strength of the acids. Hydrochloric acid is a strong acid that fully dissociates in solution, providing a higher concentration of hydrogen ions (H+) that react with calcium carbonate. In contrast, ethanoic acid is a weak acid that only partially dissociates, resulting in fewer available H+ ions. This difference in dissociation leads to a slower reaction rate with ethanoic acid, as evidenced by the equilibrium pH and the common ion effect.

PREREQUISITES
  • Understanding of acid-base chemistry, specifically strong vs. weak acids
  • Knowledge of calcium carbonate reactivity in acidic solutions
  • Familiarity with the concept of equilibrium pH
  • Basic grasp of the solubility product constant (Ksp) and common ion effect
NEXT STEPS
  • Study the dissociation of strong and weak acids in aqueous solutions
  • Explore the Ksp equations relevant to calcium carbonate
  • Investigate the common ion effect and its implications in chemical reactions
  • Learn about reaction kinetics and factors affecting reaction rates
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Chemistry students, educators, and professionals interested in reaction kinetics, acid-base reactions, and the behavior of carbonate compounds in different acidic environments.

wayneo
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explain why the reaction lumps of calcium carbonate is much slower with 0.1 M ethanoic acid than with 0.1 M hydrochloric acid at the same temperature.

any ideas?
 
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HINT: Think about what actual reacts with the calcium carbonate (think ions)
BIG HINT: One is a weak acid and the other is a strong acid.

~H
 
Consider how carbonate reacts with each respective acid in the aqueous solutions, the equilibrium pH of each respective acid solution, Ksp equation, common ion effect.
 

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