Reactivity Series: Iron in Zinc or Copper: Which Rusts Less?

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The discussion centers on the reactivity series of metals, specifically comparing the rusting of iron coated with zinc versus copper. It is established that iron coated with zinc rusts less due to the principles of galvanic cells and the sacrificial anode effect. Zinc, being more reactive than copper, sacrifices itself to protect the iron beneath it from oxidation. This confirms that the coating of zinc effectively prevents rusting of the underlying iron in aqueous environments.

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  • Understanding of galvanic cells
  • Knowledge of the reactivity series of metals
  • Familiarity with the concept of sacrificial anodes
  • Basic principles of oxidation and reduction reactions
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This discussion is beneficial for chemistry students, materials scientists, and engineers involved in corrosion prevention and metal protection strategies.

DarylMBCP
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There are two test tubes with a piece of iron soaked in water in each of them. One piece of iron has a coating of zinc while the other has a coating of copper. The question is that in which test tube is the iron least likely to rust and the answer key states that it is the piece of iron with the zinc. However, shouldn't the iron with copper be least likely to rust since zinc is more reactive than Copper so it will have a higher chance of getting oxidised and forming a solid compound, thus exposing the Iron inside? Any help is greatly appreciated. Thanks.
 
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It is not about exposing the iron, it is about galvanic cells that form. Assume that iron is all the time in contact in water and try to analyze what will happen.

You may also google for sacrificial anode.

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