Schrödinger equation and interaction Hamiltonian

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SUMMARY

This discussion focuses on the application of the Schrödinger equation in quantum mechanics, specifically regarding the interaction Hamiltonian, denoted as ##\hat{W}##. Participants clarify the relationship between the Hamiltonian ##\hat{H}##, the interaction Hamiltonian ##\hat{W}##, and the energy states ##|i\rangle## and ##|k\rangle##. The equation ##\hat{H} = \hat{H}_0 + \hat{W}## is confirmed as a valid representation, where ##\hat{H}_0## is the Hamiltonian without interaction. The energy difference between states is defined as ##k\varepsilon##, with ##\varepsilon## being the energy separation.

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  • Understanding of the Schrödinger equation
  • Familiarity with quantum mechanics terminology, including Hamiltonians and eigenstates
  • Knowledge of interaction Hamiltonians in quantum systems
  • Basic concepts of energy eigenvalues and state evolution
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TheCanadian
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Given 1A.1 and 1A.2, I have been trying to apply the Schrödinger equation to reproduce 1A.3 and 1A.4 but have been struggling a bit. I was under the assumption that by applying ##\hat{W} \rvert {\psi} \rangle= i\hbar \frac {d}{dt} \rvert{\psi} \rangle## and then taking ##\langle{k'} \lvert \hat{W} \rvert{\psi} \rangle ## and ## \langle{i}\lvert \hat{W} \rvert{\psi} \rangle## would allow me to produce 1A.3 and 1A.4. I may very well be incorrect in my methods, but did the following rough calculation and got a very different result. (In my calculation, I assumed ## \hat{W} = H ##.)

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Any clarification on how to reproduce 1A.3 and 1A.4 would be greatly appreciated.
 
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What are ##|i\rangle##, ##|k\rangle##, and ##w##? Moreover, how can you assume that ##H=W##? The answer of all of these questions should be available in the resource you have there.
 
blue_leaf77 said:
What are ##|i\rangle##, ##|k\rangle##, and ##w##? Moreover, how can you assume that ##H=W##? The answer of all of these questions should be available in the resource you have there.

## \hat {W} ## is defined as the interaction Hamiltonian. ##|i\rangle## is the initial state the system is prepared in and ##|k\rangle## are all possible states it can evolve into where k is allowed to take all values between ## - \infty ## to ## \infty ## except ##i##.
 
My guess is that ##\hat{H} = \hat{H}_0 + \hat{W}##, and that ##\varepsilon## has something to do with the energy in the absence of the interaction (i.e., the eigenvalue of ##\hat{H}_0##.

More details are needed. A reference would be nice.
 
DrClaude said:
My guess is that ##\hat{H} = \hat{H}_0 + \hat{W}##, and that ##\varepsilon## has something to do with the energy in the absence of the interaction (i.e., the eigenvalue of ##\hat{H}_0##.

More details are needed. A reference would be nice.

The initial state ## \rvert i \rangle ## has an energy equal to 0, and each state is separated in energy by a difference of ##\varepsilon##. The energy difference between ## \rvert i \rangle ## and ## \rvert k \rangle ## is k##\varepsilon##.

Sure. This is Introduction to Quantum Optics by Grynberg and this problem begins on page 34.
 
So ##\hat{H} | k \rangle = k \varepsilon | k \rangle + \hat{W} | k \rangle##. Try that in your method.
 
DrClaude said:
So ##\hat{H} | k \rangle = k \varepsilon | k \rangle + \hat{W} | k \rangle##. Try that in your method.

I got it, thank you!

Just one more question, is the statement ##\langle{i} \lvert \hat{W} \rvert{k} \rangle = w_k ## necessarily true if ##\langle{k} \lvert \hat{W} \rvert{i} \rangle = w_k ## ?

If ##\hat{W} ## was an annihilation/creation operator, it seems like this definitely would not be true. Although I had to use both relations written above when reproducing 1A.3 and 1A.4. It might just be something regarding the density matrix that I missed in the text or might be implicitly assumed.
 
I haven't done the calculation, but is the idea to calculate ##\left<k'|H|\psi \right>## twice, once using the Schrödinger equation, and once using ##H = H_0 + W## (?) together with the facts that 1) the kets are eigenstates (as in Dr. Claude's post) of ##H_0## and 2) the relations given in the original post.

Edit: TheCanadian posted while I was writing my post. This thread seems to have a surplus of Canadians.
 
TheCanadian said:
Just one more question, is the statement ##\langle{i} \lvert \hat{W} \rvert{k} \rangle = w_k ## necessarily true if ##\langle{k} \lvert \hat{W} \rvert{i} \rangle = w_k ## ?

Is ##\hat{W}## Hermitian and

$$w_k = \frac{w}{\sqrt{1+\left(\frac{k \epsilon}{\Delta}\right)^2}}$$

real?
 

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