Shouldn't the operator be applied to both the wf anD its modulus?

In summary, the two formulas presented are different ways of calculating the expectation value of a random variable in quantum mechanics. The first formula follows from the standard definition of expectation value, while the second formula is not linear and may not make as much mathematical sense. There may be a deeper reason why the first formula works, possibly related to the postulates of quantum mechanics.
  • #1
jshrager
Gold Member
24
1
Why is it:

$$ \langle A \rangle = \int dV ~ \psi^* (\hat{A} \psi) $$

As opposed to:

$$ \langle A \rangle = \int dV ~ (\hat{A} \psi^*) (\hat{A} \psi) $$

The op can substantially change the wf, so it would seem to make more mathematical sense (at least from a linear algebra pov) to operate on both the wf and its mod, otherwise, as we do it now (first expr) you're getting a very odd product. Is this is a property of the way that wfs are formulated? Are they a special case where this isn't required? Or maybe it's a magical property of hermetian operators? Or maybe it just works and I shouldn't think too hard about it.
 
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  • #2
1) it works
2) the second formula is not linear
3) There is probably some deeper reason why this works
 
  • #3
If you start with the standard definition of the expectation value of a random variable <A> = Ʃi piai -where the ais are the possible outcomes and pi is the probability to obtain the i-th- your first formula follows from the QM postulates about these quantities. I don't know if this is satifying to you. ;-)
 
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