Stuck in an Infinite Square Well

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SUMMARY

The discussion focuses on solving for the eigenstates and eigenvalues of the Hamiltonian for a one-dimensional infinite square well, specifically centered at zero and ranging from -b to b. The relevant Hamiltonian is defined as \(\mathcal{H} = -\frac{\hbar^2}{2M}\frac{d^2}{dx^2} + V\), where \(V = 0\) inside the well. The solution involves the wave function \(\psi(x) = A \sin\left(\frac{\sqrt{2ME}}{\hbar}x\right) + B \cos\left(\frac{\sqrt{2ME}}{\hbar}x\right)\), with boundary conditions leading to the conclusion that even eigenstates correspond to cosine functions and odd eigenstates correspond to sine functions.

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Homework Statement



You don't need it verbatim. I'm just trying to solve for the eigenstates and eigenvalues of the Hamiltonian for a one-dimensional infinite square well, with a particle of mass M inside. I'm embarrassed to say it, but the question is throwing me off because the infinite well is centred at zero, ranging from -b < x < b rather than from 0 < x < a.

Homework Equations



[tex]\mathcal{H}\psi(x) = E\psi(x)[/tex]

[tex]\mathcal{H} \equiv -\frac{\hbar^2}{2M}\frac{d^2 }{dx^2}\left(\right) + V()[/tex]

[tex]V = 0 \ \ \mbox{inside the well.}[/tex]

The Attempt at a Solution



Immediately from the ODE the solution is obviously:

[tex]\psi(x) = A \sin \left(\frac{\sqrt{2ME}}{\hbar}x\right) + B \cos \left(\frac{\sqrt{2ME}}{\hbar}x\right)[/tex]

[tex]\psi(b) = \psi(-b) = 0[/tex]

[tex]\Rightarrow A \sin \left(\frac{\sqrt{2ME}}{\hbar}b\right) + B \cos \left(\frac{\sqrt{2ME}}{\hbar}b\right) =0[/tex]

[tex]\Rightarrow -A \sin \left(\frac{\sqrt{2ME}}{\hbar}b\right) + B \cos \left(\frac{\sqrt{2ME}}{\hbar}b\right) =0[/tex]

I'm really not sure how to proceed. There is no value of b for which both the sine and cosine will be zero, suggesting that for some eigenstates, A is zero, and for others, B is zero. Griffiths even hints that even states are given by only cosines and odd states by sines, but I can't figure out how to arrive at this result systematically.
 
Last edited:
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I recommend you use a variable z=x+b. Then the well will be between
z=0 and z=2b, with the efunction sin(n\pi z/2b).
 

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