A white dwarf is primarily supported by positive electron degeneracy core pressure against negative gravitational core pressure within its stellar core, preventing the star from collapsing.
If the stars mass is increased, its negative gravitational core pressure also increases until a limit is approached with respect to its positive electron degeneracy pressure. If the negative gravitational core pressure exceeds its positive electron degeneracy core pressure, the star implodes and flashes a runaway carbon fusion reaction in its core and at this point the star will explode in a core-collapse Type Ia supernova, leaving behind either a neutron star or a black hole.
If a white dwarf gradually accretes mass from a binary companion, its core is believed to reach the ignition temperature for carbon fusion as it approaches the limit. Within a few seconds of initiation of nuclear fusion, a substantial fraction of the matter in the white dwarf undergoes a runaway fusion reaction, releasing enough energy (1-2 × 10^44 joules) to unbind the star in a supernova explosion.
For type II supernovae, the collapse is eventually halted by short-range repulsive neutron-neutron interactions mediated by the strong force, and neutron degeneracy core pressure.
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Reference:
http://en.wikipedia.org/wiki/Chandrasekhar_Limit"
http://en.wikipedia.org/wiki/Core-collapse_supernova#Core_collapse"
http://en.wikipedia.org/wiki/Type_Ia_supernovae"