Two particle in a square potential well?

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The discussion focuses on solving the wave function for two distinguishable particles in a two-dimensional quadratic potential well defined by the potential function V(x,y). The user attempted to apply the method of separation of variables to the Schrödinger equation but struggled to derive a sensible solution. The second part of the problem involves constructing an antisymmetric wave function for two spin-½ electrons, requiring consideration of Pauli's exclusion principle. The key takeaway is that for distinguishable particles, individual wave functions can be solved and combined, while for indistinguishable particles, the antisymmetry of the wave function must be maintained.

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H Psi equal E Psi
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Hi guys!

I'm struggling with the following problem:

Consider two distinguishable (not interacting) particles in a quadratic 2 dimensional potential well. So

##
V(x,y)=\left\{\begin{matrix}
0,\quad\quad-\frac { L }{ 2 } \le \quad x\quad \le \quad \frac { L }{ 2 } \quad and\quad -\frac { L }{ 2 } \le \quad y\quad \le \quad \frac { L }{ 2 } \\ \infty ,\quad \quad \quad rest

\end{matrix}\right.
##

I am now asked to find the normalized wave function in the ground state for two particles within the given potential. I tried to solve the schroedinger equation by means of the method of separation of variables:

##\psi ({ x }_{ 1 },{ x }_{ 2 },{ y }_{ 1 }{ y }_{ 2 })=\alpha ({ x }_{ 1 })\beta ({ x }_{ 2 })\delta ({ y }_{ 1 })\varepsilon ({ y }_{ 2 })##

This was harder then i thought so i didn't quiet got an sensible answer...

The second part of the exercise is to replace the two distinguishable particle with two spin ½ (Not interacting) electrons. Now pauli's principle has to be taken into account. Since i didn't manged to find radial function I am not able to construct the anti symmetric wave function for the electrons:

##\psi ({ x }_{ 1,2 },{ y }_{ 1,2 })=\phi ({ x }_{ 1,2 },{ y }_{ 1,2 })\cdot \frac { 1 }{ \sqrt { 2 } } ((\left| \left \uparrow \downarrow \right> \right) -(\left| \left \downarrow \uparrow \right> \right))##

While ##\phi (x,y)## is the searched function (has to be symmetric).

Sorry for my English ( not my mother tongue )

Thanks and Cheers!
 
Last edited:
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I moved the thread to our homework section.

If the particles are distinguishable and not interacting, you can solve for their wave functions individually and then combine them.
H Psi equal E Psi said:
Since i didn't manged to find radial function
Why do you want to find a radial function (a function of r?)?

Finding an antisymmetric wave function works the same as for every problem, you just have to find the ground state for a single electron.
 
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