Variational Method and Bound States

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SUMMARY

The discussion focuses on the application of the variational method to analyze bound states in quantum mechanics for a specific potential function V(x). In the one-dimensional case, it is established that the potential function always possesses at least one bound state when the parameter λ² is appropriately chosen. Conversely, in the three-dimensional spherically symmetric case, it is concluded that no bound states exist if λ² is sufficiently small. The analysis utilizes a Gaussian trial function to evaluate the average energy and its implications for bound states.

PREREQUISITES
  • Understanding of the variational method in quantum mechanics
  • Familiarity with one-dimensional and three-dimensional quantum systems
  • Knowledge of Gaussian trial functions in quantum mechanics
  • Basic concepts of bound states and energy levels
NEXT STEPS
  • Study the variational principle in greater depth, focusing on its mathematical formulation
  • Explore the implications of potential functions in quantum mechanics, particularly V(x) forms
  • Investigate the properties of bound states in three-dimensional quantum systems
  • Learn about the normalization conditions for wave functions in different dimensions
USEFUL FOR

Quantum mechanics students, physicists analyzing potential functions, and researchers studying bound states in quantum systems will benefit from this discussion.

Einj
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Homework Statement


Consider a potential function V(x) such that:
$$
\begin{cases}
V(x)\leq 0\text{ for }x\in[-x_0,x_0] \\
V(x)=0 \text{ for }x\not\in[-x_0,x_0]
\end{cases}
$$
Show, using the variational method that:

(a) In the 1-dimensional case \lambda^2V(x) always possesses at least one bound state.
(b) In the 3-dimensional spherically symmetric case, V(|\vec r|), it possesses no bound states if \lambda^2 is made sufficiently small.



2. The attempt at a solution
The idea is to use the variational method, i.e.:
$$
\frac{\langle\psi|H|\psi\rangle}{\langle \psi|\psi\rangle}\geq E_{ground},
$$
to show that the average value of the energy is negative and hence the ground state energy is negative.

In my first attempt I used a gaussian trial function:
$$
\psi(x)=\left(\frac{2a}{\pi}\right)^{1/4}e^{-ax^2}.
$$
However the problem is that it turns out that the average value of the kinetic energy is \hbar^2a/2m and so, in order to determine whether the average energy is negative or not we need to know a explicitly. However, this is not possible since we have no insight on the actual shape of the potential.

It seems to me that this thing will turn out to be a problem for every trial function. How can I do that?

Thank you
 
Physics news on Phys.org
In the 1D case the kinetic energy is proportional to ##a##. The potential energy is negative and goes as ##\sqrt{a}## when ##a## is small. Hence, if ##a## is small enough, the energy in that state will be negative, implying the existence of at least one bound state.

In the 3D case, the normalisation of the wave function gets additional factors of ##a## and the argument changes.
 

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