Variational Method - Gaussian Trial Wavefucntion

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SUMMARY

The discussion focuses on applying the variational method using a Gaussian trial wavefunction, specifically ψ(x) = Ae^{\frac{-a^{2}x^{2}}{2}}, to demonstrate that an attractive potential always has at least one bound state in one dimension. The Hamiltonian is expressed as \hat{H} = \frac{-h^{2}}{2m}\frac{d^{2}}{dx^{2}} + V(x), where the potential V(x) is unspecified. The key challenge discussed is normalizing the wavefunction and integrating the Gaussian function to find the scalar product, which is essential for proving that the trial energy can be made negative.

PREREQUISITES
  • Understanding of the variational method in quantum mechanics
  • Familiarity with Gaussian functions and their properties
  • Knowledge of Hamiltonian mechanics and kinetic energy operators
  • Ability to perform integrals involving exponential functions
NEXT STEPS
  • Learn techniques for integrating Gaussian functions, including substitution methods
  • Study the variational principle in quantum mechanics in more detail
  • Explore the implications of bound states in quantum systems
  • Review normalization conditions for wavefunctions in quantum mechanics
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Students and researchers in quantum mechanics, particularly those studying variational methods and bound states in quantum systems.

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Homework Statement


Use the variational method with a gaussian trial wavefunction ψ(x) = Ae^{\frac{-a^{2}x^{2}}{2}} to prove that in 1 dimension an attractive potential of the form shown, no matter how shallow, always has at least 1 bound state.

*Figure is of a potential V(x) that has a minimum on the negative y axis, and tends to 0 as x -> ∞ and -∞*

THERE ARE NO BOUNDARIES SHOWN ON THE DIAGRAM, THIS IS A GENERALISED POTENTIAL

HINT: prove that it is always possible to make the trial energy negative.

Homework Equations



E_{0} \geq \frac{\left\langle ψ | \hat{H} | ψ \right\rangle}{\left\langle ψ | ψ \right\rangle}

The Attempt at a Solution


We don't quite know that Hamilitonian, but we do know that it has a kinetic energy part. So I've written the Hamiltonian as:

\hat{H} = \frac{-h^{2}}{2m}\frac{d^{2}}{dx^{2}} + V(x) Since the potential is unknown at this point.

State should end up negative but larger than or equal to the bound state due to the above condition.

I tried to normal the scalar \left\langleψ|ψ\right\rangle to start things off so I could find the constant, but I have no clue on how to integrate this stupid gaussian function. I used wolfram alpha and I basically get A = \sqrt{\frac{2a}{\sqrt{\pi}}}

So I'm stuck at the first hurdle. I need to find the scalar product and then superimpose the hamiltonian and integrate to see if I meet the condition.

Otherwise, what do I need to do?
 
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Any ideas guys? It's the gaussian that's irritating me. How do I integrate it?
 

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