What Determines the Limiting Reactant in a Chemical Reaction?

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SUMMARY

The discussion focuses on determining the limiting reactant in a chemical reaction involving aluminum and oxygen, specifically the reaction represented by the balanced equation 4Al(s) + 3O2 → 2Al2O3. Participants concluded that aluminum is the limiting reactant, producing 1.56 moles of Al2O3, while oxygen produces 2.45 moles. The key to solving the problem lies in calculating the moles of each reactant and comparing them to the stoichiometric ratios in the balanced equation. The excess mass of oxygen can be determined by first calculating the moles of aluminum and oxygen present.

PREREQUISITES
  • Understanding of stoichiometry in chemical reactions
  • Knowledge of mole conversions for elements and compounds
  • Familiarity with balanced chemical equations
  • Ability to perform calculations involving molar mass
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  • Learn how to calculate moles from grams using molar mass
  • Study the concept of limiting reactants in chemical reactions
  • Explore how to convert moles of reactants to grams of products
  • Practice with additional examples of stoichiometric calculations
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Chemistry students, educators, and anyone looking to deepen their understanding of stoichiometry and limiting reactants in chemical reactions.

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Homework Statement



A mixture of 82.49g of aluminum and 117.65g of oxygen is allowed to react. Find the limiting reactant and determine the mass of the excess reactant present in the vessel when the reaction is complete.

Balanced Equation is 4Al(s) + 3O2 ----> 2Al2O3


I found that Aluminum produces 1.56 mol of 2Al2O3

and Oxygen produces 2.45 mol of 2Al2O3

So, Aluminum is the limiting reactant. I do not know how to find out the grams of Oxygen from here though.


I've been wondering since I could not do this on my first Chem exam.
 
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What is the mole ratio of Al to O2 for the these elements available to react? What is the mole ratio of Al to O2 for the theoretical written reaction? Compare these and decide which element is the limiting reactant. How many moles of the excess reactant are present at completion of the reaction? Convert this back to grams.
 
I don't understand your answer. How many moles of aluminum in 82.49 g? How many moles of O2 in 117.65 g? Start from there.
 
That's (almost) OK - 82.49 g Al -> 3.057 moles of Al -> 1.529 moles of Al2O3 - I suppose 1.56 is just a typo or math error, as results for oxygen are OK.

Chandasouk: you know how to calculate amount of Al2O3 form a given amount of O2, all you have to do is to reverse the approach. Same reaction equaton, same coefficients, just switch kgiven and unknown.

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