What happened to the photoresist (S1818) after RIE?

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SUMMARY

The discussion centers on the changes observed in photoresist S1818 after a Reactive Ion Etching (RIE) process using SF6 gas. The resist was hard baked at 125°C for 2 hours before undergoing RIE at 30 mtorr and 45 sccm for 3 minutes. Participants concluded that the color change of the resist does not indicate its removal, but rather could be attributed to factors such as sputtering, increased cross-linking from UV exposure, or incorporation of sulfur or fluorine atoms from the plasma.

PREREQUISITES
  • Understanding of Reactive Ion Etching (RIE) processes
  • Knowledge of photoresist materials, specifically S1818
  • Familiarity with plasma chemistry and its effects on materials
  • Experience with thermal processing of photoresists
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  • Research the effects of sputtering on photoresist thickness
  • Learn about the cross-linking mechanisms in photoresists under plasma exposure
  • Investigate the chemical interactions of sulfur and fluorine with photoresist materials
  • Explore troubleshooting techniques for RIE processes
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Material scientists, semiconductor engineers, and professionals involved in photolithography and etching processes who seek to understand the behavior of photoresists during RIE.

Yinxiao Li
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S1818 was hard baked at 125C for 2 hours and then put into RIE chamber. The recipe is SF6, 30mtorr, 45sccm, 3min. However, the color of the resist totally changed, as shown in the attachment.
I totally don't understand what happened here. 3 min of SF6 etching won't peel the photoresist off. Is there anybody having any ideas?
 

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Yinxiao Li said:
S1818 was hard baked at 125C for 2 hours and then put into RIE chamber. The recipe is SF6, 30mtorr, 45sccm, 3min. However, the color of the resist totally changed, as shown in the attachment.
I totally don't understand what happened here. 3 min of SF6 etching won't peel the photoresist off. Is there anybody having any ideas?
Please give more detail of what you did and what your question is. It sounds like you think that the change in color indicates that the photoresist has been removed. This is probably not the case. Probably the photoresist is still there. There are several things that could cause the color of the photoresist to change, such as:
(1) The thickness of the photoresist has changed due to some of it being sputtered away by the RIE plasma.
(2) The index of the photoresist has changed due to increased cross-linking due to exposure to the UV light from the plasma.
(3) The surface of the photoresist has changed due to incorporation of S or F atoms from the plasma.
(4) Something else...
 
phyzguy said:
Please give more detail of what you did and what your question is. It sounds like you think that the change in color indicates that the photoresist has been removed. This is probably not the case. Probably the photoresist is still there. There are several things that could cause the color of the photoresist to change, such as:
(1) The thickness of the photoresist has changed due to some of it being sputtered away by the RIE plasma.
(2) The index of the photoresist has changed due to increased cross-linking due to exposure to the UV light from the plasma.
(3) The surface of the photoresist has changed due to incorporation of S or F atoms from the plasma.
(4) Something else...

This sounds like a real profession answer! Although I cannot verify what is really going on, thank you so much for your great idea!
 

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