the duration of 9 192 631 770 periods of the radiation corresponding to the transition between the two hyperfine levels of the ground state of the caesium 133 atom
taken from wikipedia. but I remember learning it in physics.
Well, the first semi-accurate measurement of time came from pendulums. they had second pendumlums and what not. They also had mechanical clocks which showed seconds and minutes and hours like modern clocks. I doubt they were, but they could have beared a resemblance to modern day grandfather clocks. they based there days off of the ascension of stars.