WannabeNewton,
You say that the characteristic length is an intrinsic property of the system, yet your one example would say otherwise. The de Broglie wavelength of a given particle varies inversely with its momentum, and this can also be related to the temperature. Thus, as the temperature varies, the de Broglie wavelength varies;
An inherent property would be something that does not change even when its environment is changing in every way.
It would seem that the characteristic length would have to be something that varies, for if it did not, we would never observe classical theories being valid in one case, and then, when the characteristic length varies because environmental conditions are varying, valid in another case.
I imagine it would the some parameter of the system that, when varied, causes Quantum Mechanical effects to be manifest; this parameter makes the laws of Quantum Mechanics necessary, if we are to properly describe the behavior of the system. And so, not only does the characteristic length change when the environmental conditions change, but what the characteristic length is, changes when the system is placed in a completely different environment.
For example, suppose we have some particles placed in contact with some heat source. As the temperature varies, so does the de Broglie wavelength; when it changes, certain Quantum effects either manifest or disappear. So, the characteristic length is the de Broglie wavelength. Now, take this same system of particles, and by some means, propel them near the speed of light, certain relativist effects manifest. Thus, for the same system, the characteristic length has changed in two different ways.
I don't intend to cause any dissension, I am simply trying to search out a good definition of characteristic length
EDIT: Now that I have re-read your post, I believe I might have just said the same thing you did.