What is the coffee ring of toluene and hexane?

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    Coffee Ring Solvent
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SUMMARY

The discussion centers on the phenomenon of coffee rings formed by the evaporation of droplets containing dissolved substances, specifically focusing on toluene and hexane. It is established that while pure deionized (DI) water does not leave a ring due to the absence of dissolved solids, both toluene and hexane can leave a ring upon evaporation, indicating the presence of impurities. The purity of toluene is noted to be 95%, suggesting that even high-purity solvents can contain dissolved substances that contribute to this effect. Factors such as the cleanliness of the glass substrate and the surrounding environment are also critical in understanding the formation of these rings.

PREREQUISITES
  • Understanding of solvent properties and evaporation processes
  • Knowledge of purity standards for laboratory chemicals
  • Familiarity with the concept of surface tension and its effects on droplet behavior
  • Basic principles of contamination and cleanliness in laboratory settings
NEXT STEPS
  • Research the effects of impurities in organic solvents like toluene and hexane
  • Explore methods for measuring the purity of laboratory chemicals
  • Learn about the physics of droplet evaporation and ring formation
  • Investigate cleaning protocols for glass substrates in laboratory experiments
USEFUL FOR

Chemists, laboratory technicians, and anyone studying solvent behavior and contamination effects in experimental setups will benefit from this discussion.

Yinxiao Li
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When we drop a coffee droplet and wait for it to evaporate, there is a coffee ring left. Because there is coffee dissolved in the solution, and when water can evaporate into the air, the coffee cannot evaporate and it will stay.

Therefore, if we drop one DI water droplet onto the substrate, there will be no such ring left because nothing is dissolved in the DI water.

Here comes the question: when I droplet one droplet of Toluene or Hexane onto a glass substrate, there is a ring after it evaporates! Toluene and Hexane are newly bought, and they should be good and pure. Then what does this ring come from? It means something is dissolved in the Hexane and Toluene. Any clues?
 
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Do you know the purity of your toluene or hexane?
 
Similarly, how clean is the glass? How clean is the room the glass/droplet are sitting in?
 
256bits said:
Do you know the purity of your toluene or hexane?
you are right. Toluene is 95% pure.
 

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