What is the definition of 'ground state',considering H- ion = -14.35eV

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The discussion clarifies the definition of 'ground state' in quantum mechanics, specifically in relation to the hydrogen atom (H) and the hydrogen anion (H-). The ground state is defined as the lowest energy state of a system, which for the hydrogen atom is -13.6 eV, while the hydrogen anion has a lower energy of -14.35 eV. However, H- is not classified as a ground state because it represents a different system with distinct energy levels, not merely an extension of the proton-electron system. The orbital notation for the H- ion is confirmed to be 1s2.

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If 'ground state' is the lowest energy state, and H atom takes -13.6eV to ionise while H- takes -14.35eV, why is H- not considered the 'ground state'?

Is that definition wrong? What is the definition of 'ground state' that "fixes" this?
 
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Ground state of an electron in a proton-electron system (by which I mean the system consisting of one proton and one electron) would be the lowest energy state available to the electron.

H- is not a proton-electron system. That's a different system with a different set of energy levels available to the electrons.
 
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OK, got it.

In orbital notation, what is the H- ion? Is it 1s2?
 

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