What is the Force Constant for Gaseous 14N16O?

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Homework Help Overview

The discussion revolves around calculating the force constant for gaseous 14N16O using the simple harmonic oscillator model, given its fundamental vibrational frequency of 1904 cm-1.

Discussion Character

  • Conceptual clarification, Mathematical reasoning, Assumption checking

Approaches and Questions Raised

  • Participants explore the relationship between vibrational frequency and force constant, questioning the interpretation of frequency given in cm-1 and its conversion to Hz.

Discussion Status

Some participants have pointed out potential misunderstandings regarding the terminology used, particularly the distinction between frequency and wavenumber. There is an ongoing examination of how to appropriately convert wavenumber to frequency for the calculations.

Contextual Notes

Participants are discussing the implications of using wave numbers in the context of the problem and how this affects the calculations for the force constant.

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Homework Statement


The fundamental vibrational frequency of gaseous 14N16O is 1904 cm-1.

a. Calculate the force constant, using the simple harmonic oscillator model


Homework Equations



K=u((2pi)(v))^2 u=reduced mass

The Attempt at a Solution



u=[(14)(16)/(30)] (1kg/6.02e^26)= 1.24e^-26 Kg/molecules

K=(1.24e^-26 kg)((2pi)(1904 cm^-1))^2= 1.77e^-22 kg m^2

How do I get the answer in N/m ??
 
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What does it mean when there is a frequency given in cm-1? Frequency should be given in Hz (or per time of some sort). Perhaps instead of "fundamental frequency" they meant "wave number/vector"?
 
cm^-1 is the wavenumber.
 
If you have K = u(2pi*v) why are you plugging in your wave number for v? v is a frequency yes? So how do you convert a wave number into frequency?
 
Ok...

Good point, I will change wave number to frequency.
 

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