Are you sure there is one? Wikipedia's list of accidental isomorphisms only extends up to spin(6) (universal covering of SO(6)), and that's it.
A quick google search results that Spin(8) has SU(4) and SP(2) as subgroups, but that's about all I could find. Since SU(4) has dimension 15, and SO(8) has dimension 28, I can't see a way of making this work out on dimensional grounds. Perhaps someone more knowledgeable than me can answer this.
EDIT: After looking at Wikipedia more closely, I don't think this can be done. Wikipedia says SO(8) is simple, and so it can only be isomorphic to one factor of SU(n), and since SU(4) has dim 15, and SU(5) has dim 24, and SU(6) has dim 35, it doesn't seem like the dimensions match up.