It's not just a matter of a certain length scale--time scales and mass scales also matter. The physical constant ##\hbar## determines whether quantum mechanics is important or whether classical mechanics is a good approximation. To figure out if quantum mechanics is likely to be important, express ##\hbar## in units appropriate to your situation. For example, in our daily lives we work on length scales of order 1 meter, time scales of order 1 second, and mass scales of order 1 kilogram. Expressed in these units, ##\hbar## is
##\hbar \approx 10^{-34}## kg m^2 /s
##10^{-34}## is much smaller than 1, so classical mechanics is fine in ordinary life.
Now, electrons in atoms are confined to regions of order 1 nanometer, orbit the nucleus in timescales of order 1 femtosecond, and weigh of order ##10^{-30 kg}##. Expressed in these units we have
##\hbar \approx 0.1## (10^(-30) kg) nm^2 / fs
0.1 is not so small compared to 1, so QM is important for electrons in atoms.