Why is amorphous glass more transparent than crystalline materials?

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well if free electrons are the fundamental cause of reflection, how do you explain total internal reflection from glass?
 
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light is NEVER totally internally reflected. Even after the critical angle, there still exists a beam propagating along the surface (eg. the evanescent wave - which is another philosophical issue...)
 
but that's applicable to metals too..
leave it what i meant was just that free electron theory alone is not sufficient to explain reflection from all surfaces
 
Raze2dust said:
but that's applicable to metals too..
leave it what i meant was just that free electron theory alone is not sufficient to explain reflection from all surfaces

I agree.
 
To me, asking, "Why is glass 'see-through'? " is the same as asking, "Why is 'air' 'see-through'? ".
 
rewebster said:
To me, asking, "Why is glass 'see-through'? " is the same as asking, "Why is 'air' 'see-through'? ".

sure...because air and glass have the same material structure...:rolleyes:
My intention of this thread was to understand how light interacts with amorphous glass upon propagation.