Why is the equation for a sodium-sulfur battery reaction considered 'not right'?

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Discussion Overview

The discussion revolves around the chemical equation for the reaction in a sodium-sulfur battery, specifically addressing why a participant's representation of the reaction was deemed 'not right' by their teacher. The scope includes theoretical aspects of redox reactions and the chemistry involved in sodium-sulfur batteries.

Discussion Character

  • Homework-related, Technical explanation, Debate/contested

Main Points Raised

  • One participant presents the equation 2Na + 3S --> Na2 + S3^2- and notes it as a redox reaction with two electrons transferred.
  • Another participant suggests that the correct representation might be 2Na + 3S <----> Na2S3, indicating a possible misunderstanding of the reaction's stoichiometry.
  • A different viewpoint proposes changing Na2 to 2Na+, implying a need for clarity in the ionic representation.
  • One participant comments on the complexity of sodium-sulfur chemistry, suggesting that the reaction may not be straightforward and involves various polysulfides, which might not be easily reproduced in a typical school laboratory setting.
  • This participant also mentions that the representation of S3^2- might be a convention, hinting at the existence of other polysulfide species like S2- and S22- that could be present in the reaction.

Areas of Agreement / Disagreement

Participants express differing views on the correctness of the initial equation, with some suggesting alternative representations and others highlighting the complexity of the chemistry involved. The discussion remains unresolved regarding the accurate depiction of the reaction.

Contextual Notes

There are limitations regarding the assumptions made about the reaction conditions and the representation of polysulfides, which may not be fully addressed in the discussion.

Creaturemagic
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2Na + 3S --> Na2 + S3^2-

Homework Statement



So I have the equation 2Na + 3S --> Na2 + S3^2- (the 2- being the charge of S3)
This is the reaction generated in a sodium-sulfur battery.
And all's good there, I can see there are two electrons transferred in the reaction and I know it's a redox reaction. However when I handed in my draft for this piece of assessment, I got it back with the comment that this reaction didn't look 'right'.

The task at hand is to summarise an article (Mine being on Electric Cars) and then write four 'focus' questions and model answers. So the reaction is taken straight from the article and I just don't see how it isn't right.

Thanks for any help clearing this up, I plan to ask my teacher tomorrow, so I'll keep this updated.
 
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Or change Na2 to 2Na+...
 
It could well not look right because that is not everyday chemistry - you will have seen it works in quite hairy conditions not to be reproduced in a school laboratory.

I don't know anything but looking at this http://en.wikipedia.org/wiki/Sodium–sulfur_battery and the book extract it looks like it's a mix of polysulfides all the way down and even further than S32- so, as they say it's a bit of a convention to fix on S32-. I expect you can get some S22- and S2-, perhaps they are not wanted.
 

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