Writing Simple Equations for Combining HCl with Elements from the Carbon Group

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Discussion Overview

The discussion revolves around writing chemical equations for the reaction of hydrochloric acid (HCl) with elements from the carbon group, specifically carbon (C), silicon (Si), tin (Sn), and lead (Pb). Participants are seeking clarity on the correct stoichiometry and oxidation states involved in these reactions.

Discussion Character

  • Technical explanation, Homework-related, Debate/contested

Main Points Raised

  • One participant presents an initial equation for the reaction of carbon with HCl, suggesting C + 2HCl --> C(Cl)2 + H2, but expresses uncertainty about its correctness.
  • Another participant questions the oxidation state of carbon after the reaction and suggests that carbon may form CCl4 instead of C(Cl)2.
  • A later reply mentions the simplicity of the lab setup, where a piece of solid carbon was dropped into HCl, and raises a question about the correct equation for lead, proposing two different possibilities: 2HCl + Pb --> PbCl2 + H2 or 4HCl + Pb --> PbCl4 + H4.
  • One participant advises looking up or calculating the final oxidation states of the elements involved, noting that carbon tetrachloride (CCl4) is a common compound formed by carbon.
  • There is a correction regarding the representation of hydrogen in the equations, clarifying that it should be H2 rather than H4.

Areas of Agreement / Disagreement

Participants express differing views on the correct products and stoichiometry of the reactions, particularly regarding carbon and lead. There is no consensus on the correct equations or oxidation states.

Contextual Notes

Participants mention the need for balanced equations and oxidation states, indicating that some assumptions or calculations may be required to arrive at the correct representations. The discussion does not resolve these uncertainties.

Who May Find This Useful

This discussion may be useful for students and educators involved in chemistry labs, particularly those focusing on reactions involving hydrochloric acid and group carbon elements.

lifendeath
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I am doing the write up for one of my labs. In this write up we combined HCl with some of the elements from from the Carbon group (C, Si, Sn, Pb).

Naturally, my professor wants us to express what occurred in equation form. But I am not sure if I am doing it correctly... here is what I have so far:

C + 2HCl --> C(Cl)2 + H2

I didn't want to continue with the other 3 elements just in case I'm doing it wrong...So any insight would be greatly appreciated.

Thank you!
 
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Do you know what oxidation state the carbon ended up in?
Did you weight the reactants to determine how much C an Cl are used or are you supposed to know this from the chemistry?

I would have though C would go to C Cl4
 
mgb_phys said:
Do you know what oxidation state the carbon ended up in?
Did you weight the reactants to determine how much C an Cl are used or are you supposed to know this from the chemistry?

I would have though C would go to C Cl4

Honestly put, this was a very basic lab. We simply dropped a small piece of solid Carbon into a beaker-full of HCl.

For the Pb would the equation be: 2HCl + Pb --> PbCl2 + H2 OR 4HCl + Pb --> PbCl4 + H4?
 
You need to look up (or you could calculate it - but this is rather more advanced) what the final oxidation state of the carbon (etc) is eg C 2+ or C 4+.
then you just need to write a balanced equation to work out how man HCl you need to add to get to that.

Carbon tetrachloride is a common solvent so carbon definitely forms C Cl4 - I don't know about the others.

ps. It wouldn't be 2H or 4H since Hydrogen forms a molecule of 2 atoms, it would be H2 or 2 H2
 

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