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gulsen
Jan11-07, 08:23 AM
How much sense does it make to compute expectation value of an observable in a limited interval? i.e.

\int_a^b \psi^* \hat Q \psi dx.
rather than
\int_{-\infty}^{\infty} \psi \hat Q \psi dx

Apparently, it shouldn't make any sense for it gives weird results when you compute e.v. of momentum for a part of infinite potentital well (say well is [0,a] and you do the e.v. integral from [0,a/3]]). Why do we have to integrate over all the space then?

dextercioby
Jan11-07, 08:53 AM
In the position representation, \psi (x) is well defined on all real axis, even though the system might be constrained to "move" in a box.

Daniel.

PRB147
Jan31-07, 11:35 PM
you must integrate over entire space!
For infinite potential, there in no leak for
wavefunction beyond the potential boundary.