I shot schrodinger's cat and then I ate it

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Homework Help Overview

The discussion revolves around solving the Schrödinger equation for a one-dimensional particle in a box, specifically focusing on the form of the wavefunction and its relation to wave equations. Participants are exploring the transition from classical wave equations to quantum mechanical representations.

Discussion Character

  • Exploratory, Conceptual clarification, Mathematical reasoning

Approaches and Questions Raised

  • Participants are questioning the relationship between angular frequency (omega) and energy, as well as the transition from sine to cosine forms in wavefunctions. There is also confusion regarding boundary conditions and the derivation of the wavefunction from the Schrödinger equation versus classical wave equations.

Discussion Status

The discussion is ongoing, with participants providing insights into the connections between different equations and forms. Some guidance has been offered regarding the nature of boundary conditions and the implications of choosing different initial conditions, but no consensus has been reached on the specific relationships or derivations.

Contextual Notes

Participants note that important information may be missing from the original post, which could affect the clarity of the problem. There is also mention of the need to focus on the forms of differentials rather than constants in the equations discussed.

Just some guy
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I'm currently reading up about solving the Schrödinger equation for a one-dimensional particle in a one-dimensional box with an infinite level of potential outside the box, and I have a *slight* problem (no, really, it is very slight)

I've got to the equation where the Wavefunction = Acos(2*x*pi/lambda - omega*t). And the text I'm working on says that using the Planck relationship omega is equal to energy? ey! I was under the impression that omega equalled angular velocity (not that I have a clue why a wave would have angular velocity, but that's another story).

Besides, I'm not entirely sure how that equation is in the form it is - the wave equation arrived at by modelling a traveling 1-d wave comes to Asin(2*pi/lambda(x ± vt). Firstly, how does that get to a cos expression (is that just coming from using different initial conditions where in the first case x = A at t = 0 (well, psi, or whatever) and x = 0 at t = 0 in the second? That leaves the omega*t bit of the first equation - I'm assuming that is equivalent to 2*pi*vt/lambda from the traveling wave equation - how do those two relate?

And finally where did the minus sign go from the second equation?

Blech, sorry for the convoluted post, I'm not really this confused! honest!:rolleyes:

Cheers,
Just some guy
 
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You really have not provide sufficient information for anyone (at least for me) to accurately address this specific problem. You present a rather specific form of the answer or end result, but you left out important info on the nature of the problem.

Just some guy said:
I've got to the equation where the Wavefunction = Acos(2*x*pi/lambda - omega*t). And the text I'm working on says that using the Planck relationship omega is equal to energy? ey! I was under the impression that omega equalled angular velocity (not that I have a clue why a wave would have angular velocity, but that's another story).

[tex]E = hf[/tex]

But [tex]f = \frac{\omega}{2 \pi}[/tex]

So [tex]E = \frac{h \omega}{2 \pi}[/tex]

or [tex]E = \hbar \omega[/tex]

This means that [tex]\omega[/tex] is equivalent to energy except for a Planck constant.

Besides, I'm not entirely sure how that equation is in the form it is - the wave equation arrived at by modelling a traveling 1-d wave comes to Asin(2*pi/lambda(x ± vt). Firstly, how does that get to a cos expression (is that just coming from using different initial conditions where in the first case x = A at t = 0 (well, psi, or whatever) and x = 0 at t = 0 in the second? That leaves the omega*t bit of the first equation - I'm assuming that is equivalent to 2*pi*vt/lambda from the traveling wave equation - how do those two relate?

This is where you left out quite a bit of info. The form of the solution to the wavefunction depends on where you choose x=0. If you choose it to be at one of the walls, then your solution will always be of the sine form due to the boundary condition. But if you choose to be at the center of the well, then it will be an alternating sine and cosine functions.

I'm a bit confused when you indicated that the wave equation was "... arrived at by modelling a traveling 1-d wave...". Did you not solve this from the Schrödinger equation? If you did, then there is no "modelling" of any kind. It's just solving the differential equation via brute force and that's that.

Zz.
 
ZapperZ said:
I'm a bit confused when you indicated that the wave equation was "... arrived at by modelling a traveling 1-d wave...". Did you not solve this from the Schrödinger equation? If you did, then there is no "modelling" of any kind. It's just solving the differential equation via brute force and that's that.

Well, the text I'm reading got the equation from solving the wave equation for an ideal string: d^2y/dx^2 = (p/t)d^2y/dt^2, to which the solution is y(x,t) = Asin((2pi/lambda)(x±vt))
 
Just some guy said:
Well, the text I'm reading got the equation from solving the wave equation for an ideal string: d^2y/dx^2 = (p/t)d^2y/dt^2, to which the solution is y(x,t) = Asin((2pi/lambda)(x±vt))

Yes, now look at the time-independent Schrödinger equation for V=0, and see if you see the connection. Then look at the boundary conditions.

Zz.
 
you mean -h-bar^2/2m*((d^2)psi/dx^2) = E*psi? Sorry, I don't see the relation - does h-bar/2m relate to p/t?
 
Er.. I goofed. I should have said time DEPENDENT Schrödinger equation.

Don't pay attention to the h-bar, etc... those are just constants. Pay attention to the FORM of the differentials.

Zz.
 
ZapperZ said:
Er.. I goofed. I should have said time DEPENDENT Schrödinger equation.

Don't pay attention to the h-bar, etc... those are just constants. Pay attention to the FORM of the differentials.

Zz.

ok, so the partial derivatives are sort of equivalent - I don't get the connection though.

Basically I don't get how one reaches the wavefunction for an electron (=Acos((2*pi*x/lambda) * (omega*t)) from the expression for a traveling wave in one dimension - y(x,t) = Asin(2*pi/lambda)*(x±vt)

The opening text says "Starting with the expression for a traveling wave in one dimension, the connection can be made to the Schrödinger equation." - I just don't get how
 

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