Recent content by kalery

  1. K

    Undergrad Tunneling through a PE barrier

    I'm still in Intro Physics, and I'm a little perplexed by the concept of tunneling. An alpha particle escapes the nucleus by overcoming a potential energy barrier created by Coulombic repulsion with the protons of the nucleus, but this is a spontaneous process and does not require E input...
  2. K

    Organic Chemistry: acid pKa of a substituted phthalic acid

    Here's why I think he may have made up the pKa values: The pKa's for phthalic acid (the 1,2-dicarboxylic acid of benzene) are pKa1 = 2.98 and pKa2 = 5.28. What this would mean is that somehow phthalic acid is more acidic than 3-bromo-4-nitrophthalic acid (pKa1 = 3.50), which we know cannot be...
  3. K

    Organic Chemistry: acid pKa of a substituted phthalic acid

    Thank you for responding. I read over these thoughtful replies several times. Interesting comments! I still think the professor's reasoning for his answer is specious and incorrect. Without verifiable published pKa's, it's my word against his *sigh*
  4. K

    How Do You Determine Which Substance Has the Highest Melting Point?

    Nope. Ionic bonds are stronger than covalent bonds.
  5. K

    How Do You Determine Which Substance Has the Highest Melting Point?

    Ionic compounds melt at higher temperatures, because it takes more energy to break the crystal lattice structures they form. In general, the stronger and more polar the bonding for the molecule, the higher the melting point.
  6. K

    Organic Chemistry: acid pKa of a substituted phthalic acid

    Homework Statement Two protons have different pKas: 3.50 and 4.25. The molecule is 2-bromo-3-nitrophthalic acid (if I'm naming it correctly). Assign the correct pKa to each proton. http://uploader.ws/upload/200805/pkablank.jpgHomework Equations A lower pKa means a stronger acid, which means...
  7. K

    Estimate pH of KMnO4: Is It Neutral?

    it's a highly oxidized salt
  8. K

    Questions Chiral centers,Markonikov's rule

    Question 1: part c) H2S is a product, not a reactant. part d) You're missing a chiral center. The 4-position Carbon is chiral for the elimination products. It's not quite symmetrical. bonus looks correct!
  9. K

    Are My Test Review Answers Correct?

    On problem #3 you need to convert the mass to kilograms when calculating the mass-per-unit-length in the velocity equation. Your numbers will turn out more reasonable. 22 m/s on a short string seems a bit much :p
  10. K

    Mirror Word Problem: Focal Length & Image Characteristics

    The fact that a real image is projected onto the screen in part 1 suggests you have a concave mirror. When an object is placed outside the focal length of the mirror in part 2, the image is real, inverted, and diminished.
  11. K

    How can I accurately calculate distance using sound and various variables?

    On question 1, the sound waves travel to the ocean surface, then travel back to the boat. Going down, gravity acts, which means you need an equation for constantly accelerating motion (y,yo,.5gt^2 etc). Going up, you can apply the simple velocity equation t=d/v. Using this information in...
  12. K

    Why does the OH react with HA and not H3O+?

    Hydroxide deprotonates weak acids and hydronium ion alike. In a basic solution, hydroxide abstracts acidic protons from both molecules.
  13. K

    Chemistry Problems: Can You Help Me Solve These Three?

    HOFO can be written as a neutral species, I think. H-O-F=O with two lone pairs on Fluorine The central atom of SiCl2Br2 is Si, and its geometry is tetrahedral, with no lone pairs.The electron dot structure is hard to input here, so I'll describe it. C with a single bond (:) to H and a single...
  14. K

    Does the reaction between H2SO4 and NH4OH produces ammonia?

    Sulfuric acid acidifies your system and protonates any ammonia that is formed.