Why does the OH react with HA and not H3O+?

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SUMMARY

In the titration of a weak acid (HA) with a strong base, hydroxide ions (OH-) preferentially react with HA rather than hydronium ions (H3O+) to achieve neutralization. This occurs because hydroxide ions effectively deprotonate HA, leading to the neutralization of remaining HA molecules. The reaction dynamics favor the interaction between OH- and HA over H3O+, as hydroxide can abstract protons from both species but is more effective in neutralizing the weak acid directly.

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motornoob101
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In titrating HA, the weak acid with a strong base, why does the OH- ions from the strong base react with the HA atom (and neutralize it) rather than say react with the H3O+ to form complete neutralization? Just curious. Thanks.
 
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HA donates protons to water regardless of whether the base is present or not however the hydroxide can neutralize the remaining HA molecules. Ultimately hydroxide is going to prefer the latter over the former.
 
motornoob101 said:
In titrating HA, the weak acid with a strong base, why does the OH- ions from the strong base react with the HA atom (and neutralize it) rather than say react with the H3O+ to form complete neutralization? Just curious.
Thanks.

Hydroxide deprotonates weak acids and hydronium ion alike. In a basic solution, hydroxide abstracts acidic protons from both molecules.
 

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