Acid-Base Reactions: Is it Always a One-to-One Relationship?

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Discussion Overview

The discussion revolves around the classification of acid-base reactions, particularly whether a chemical that reacts with an acid is always considered a base and vice versa. Participants explore the definitions of acids and bases and the nature of specific chemical reactions, including a reaction involving sulfur and sodium hydroxide.

Discussion Character

  • Debate/contested
  • Conceptual clarification
  • Technical explanation

Main Points Raised

  • One participant questions whether a chemical reacting with an acid is always classified as a base, using the reaction of sulfur with sodium hydroxide as an example.
  • Another participant notes that the classification of acid-base reactions depends on the definition used, mentioning the Arrhenius, Bronsted-Lowry, and Lewis definitions.
  • A participant suggests that the reaction in question is too complex to be classified simply as an acid-base reaction.
  • There is a suggestion that while the overall reaction may not be an acid-base reaction, some stages of the reaction could qualify as such.
  • One participant seeks clarification on whether sulfur is considered an acid in the context of the reaction discussed.
  • Another participant confirms that sulfur is not classified as an acid in this reaction.

Areas of Agreement / Disagreement

Participants express differing views on the classification of the reaction and the definitions of acids and bases. There is no consensus on whether sulfur can be classified as an acid in the given reaction.

Contextual Notes

The discussion highlights the complexity of chemical reactions and the varying definitions of acids and bases, which may influence the classification of reactions. The specific nature of the reaction involving sulfur is acknowledged as being complex and not easily categorized.

Knightycloud
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Lets say a certain chemical reacts with an acid. Does that make that chemical a base always and vice versa?

Like in S + NaOH → Na2S + Na2S2O3, Sulfur reacting with a base would it make S an acid?

Or do we call it a base or an acid, reacting with the opposite if it's producing water as a byproduct?
 
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What classifies as an acid-base reaction depends on the definition of acid and base (and there are many, three most often used are Arrhenius definition, Bronsted-Lowry def. and Lewis def.).

Reaction you listed is too complex to be classified as a simple acid-base reaction, no matter which definition you use.
 
So it is just a redox reaction, no acid base reaction? :)
 
You can put it this way. It is hardly a single step reaction, so it is quite possible some of the stages qualify as acid-base reactions.
 
But Sulfur is not an acid in this reaction, right?
 
No, it is not.
 
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:smile: That's all I want to know. Thank you!
 

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