Acid/Base Titration: 200.0 mL of 0.100 M (C2H5)2NH & 0.100 M HCl

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Discussion Overview

The discussion revolves around the titration of 200.0 mL of 0.100 M (C2H5)2NH with 0.100 M HCl, specifically focusing on determining the pH at the equivalence point of the titration. Participants explore concepts related to buffer solutions and the application of the Henderson–Hasselbalch equation.

Discussion Character

  • Homework-related, Conceptual clarification, Debate/contested

Main Points Raised

  • One participant expresses uncertainty about how to approach the problem and seeks assistance in understanding the titration process.
  • Another participant clarifies that the pH at the equivalence point does not necessarily equal 7, emphasizing that it depends on the nature of the acid and base involved.
  • Some participants discuss the concept of buffer solutions, noting that there is no buffer at the equivalence point, although there may be arguments for its existence.
  • There is mention of the Henderson-Hasselbalch equation, with one participant suggesting it may not be applicable at the equivalence point.
  • A participant provides a link to a resource for calculating the pH at the equivalence point.
  • One participant expresses gratitude for the discussion despite it being too late to assist their friend.

Areas of Agreement / Disagreement

Participants generally agree that the pH at the equivalence point is not necessarily 7 and that the Henderson-Hasselbalch equation may not be applicable in this context. However, there is some contention regarding the existence of a buffer at the equivalence point.

Contextual Notes

Participants do not fully resolve the applicability of the Henderson-Hasselbalch equation at the equivalence point, nor do they clarify the specific pH range expected for the titration in question.

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Homework Statement


Supposed to rank a bunch of titrations in order of pH; Here is one of the many...
200.0 mL of 0.100 M (C2H5)2NH (Kb = 1.3 x 10-3) by 0.100 M HCl

Homework Equations


Henderson–Hasselbalch equation?

The Attempt at a Solution


I don't even know where to start, I'm trying to help a friend (obv. doing a great job).
If someone could help do this one I think I'll remember how to do these questions.
 
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I mean the pH at the equivalence point of the titration
 
stlrams_fan said:
I mean the pH at the equivalence point of the titration

What it sounds like you are looking for are the various pH ranges that every buffer has. The equivalence point is when the moles of acid = moles of base (not necessarily pH=7); so various inorganic and organic buffers will have equivalence points in certain ranges that are suitable to various applications, i.e. reactions. You can use the H.H. equation and known pKa value to calculate pH for various buffers
 
gabriels-horn said:
What it sounds like you are looking for are the various pH ranges that every buffer has.

There is no buffer at the equivalence point.

Well... technically you can argue that it exists. But Henderson-Hasselbalch equation will fail miserably.
 
Sorry for the last reply, your replies were too late to help my friend. But I still want to know for my own benefit, so thanks.
 

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