Acids, Bases, and Salts: Essential Equations and Laws for Success in Class

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Discussion Overview

The discussion revolves around the essential equations and concepts related to acids, bases, and salts, particularly in the context of a new chapter unit for a chemistry class. Participants seek to clarify important information, including equations, laws, and problem-solving strategies relevant to the topic.

Discussion Character

  • Homework-related
  • Technical explanation
  • Conceptual clarification
  • Exploratory

Main Points Raised

  • One participant inquires about important equations and laws to prepare for a chapter on acids, bases, and salts.
  • Another participant lists key topics including the Henderson-Hasselbalch equation, the formation of water, equilibrium theory, neutralization equations, and titration curves, suggesting that practice is essential.
  • A participant expresses confusion about titration curves and receives an explanation about their significance and how they are constructed.
  • There is a request for clarification on the Henderson-Hasselbalch equation, which one participant notes is not included in their notes.
  • Another participant provides a link for further information on the Henderson-Hasselbalch equation and mentions the ICE table method as an alternative approach.
  • A note is made regarding the limitations of the Henderson-Hasselbalch equation, particularly its applicability under certain conditions.

Areas of Agreement / Disagreement

Participants express varying levels of understanding and familiarity with the concepts discussed, particularly regarding titration curves and the Henderson-Hasselbalch equation. There is no consensus on the best approach to these topics, and some participants highlight limitations of certain equations without resolving the overall discussion.

Contextual Notes

Some participants mention specific conditions under which the Henderson-Hasselbalch equation is applicable, indicating that its use may depend on the concentrations of the solutions involved.

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[SOLVED] Acids, Bases, and Salts

I will be starting on a new chapter unit of Acids, Bases, and Salts for class. I was wondering what important information I should be aware of, like equations and laws since I want to stay ahead of my class, and not die if I miss a day.
 
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Derivations of the Henderson-Hasselbach equation as well as the normal pH equation

The equation of the formation of water as well as the related equilibrium theory equations

The neutralization equation of an acid and base

pH problems where the acid or base is neutralized and then asks for the pH

Titration curves including the pH=pKa point - essentially there's a lot to this chapter my advice is that you practice a lot of problems.
 
Cool, just had chemistry today, went over the introductory parts of the unit. We've gone over the equation of the formation of water, and the conjugate bases, and acids of each acid or base. What are titration curves though?
 
xnonamex0206 said:
Cool, just had chemistry today, went over the introductory parts of the unit. We've gone over the equation of the formation of water, and the conjugate bases, and acids of each acid or base. What are titration curves though?

You will probably find titration curves easy to understand just as you found acids and bases and salts to be easy to understand after you read those sections in your book. From your question, you are probably in a General Chemistry course and you never took/enrolled in a Chemistry course before. The simpler Chemistry courses will not likely deal with titration curves. THE ANSWER: A person can add a standard concentration of a known acid or base to a solution containing a base or acid to neutralize it, and measure pH after each addition of the standard solution. The graph of data points of volume of standard solution (called the titrant) with corresponding pH is a titration curve. You then have a picture showing pH as a function of volume of titrant.
 
Actually, haha Tritation curves come up later up in the chapter. Thanks for the explanation. Now I can have an early understanding for them.

Derivations of the Henderson-Hasselbach equation as well as the normal pH equation

Could someone explain Henderson-Hasselbach though, this doesn't seem to be in my notes.

Also what is RICE?
 
xnonamex0206 said:
Could someone explain Henderson-Hasselbach though, this doesn't seem to be in my notes.

look here http://www.biology.arizona.edu/biochemistry/problem_sets/ph/HH.html

but if it is not in your textbook, then you may be doing it with an ICE table (longer and more work IMO)

I= initial concentration
C = change in concentration
E = equilibrium concentration
 
Thank you I wrote down the equations that were listed on the website.
 
Note: Henderson-Hasselbalch equation has its limitations and can't be used blindly. For solutions above 10 mM and acids weaker than pKa 2.5, Henderson-Hasselbalch equation gives results with acceptable error. That's assuming you use it to calculate pH of the solution simply putting HA and A- concentrations calculated from neutralization stoichiometry.


ChemBuddy chemical calculators
 
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