Allowed energies for electrons in hydrogenic atoms

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SUMMARY

The discussion clarifies the equations for allowed energies of electrons in hydrogenic atoms: E = -\frac{hcRZ^2}{n^2} and E = -\frac{RZ^2}{n^2}. Both equations are valid, but they differ in the definition of R. In the first equation, R represents a constant with dimensions of 1/length derived from the Rydberg formula, while in the second equation, R is the Rydberg unit of energy, which is dimensionally energy and corresponds to the ground state energy of the hydrogen atom. The atomic unit of energy, known as the hartree, is equivalent to two Rydbergs.

PREREQUISITES
  • Understanding of quantum mechanics principles
  • Familiarity with atomic structure and hydrogenic atoms
  • Knowledge of the Rydberg formula and its applications
  • Basic grasp of energy units in physics, specifically the hartree
NEXT STEPS
  • Study the derivation of the Rydberg formula for hydrogenic atoms
  • Learn about the significance of the Rydberg unit of energy
  • Explore the concept of atomic units, particularly the hartree
  • Investigate the implications of infinite nuclear mass approximation in quantum mechanics
USEFUL FOR

Students of quantum mechanics, physicists specializing in atomic physics, and educators seeking to clarify energy levels in hydrogenic atoms will benefit from this discussion.

manenbu
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I have a question which may seem stupid, but I think I missing something here.

I see 2 equations describing allowed energies for electrons in hydrogenic atoms, being:
E = -\frac{hcRZ^2}{n^2}
And
E = -\frac{RZ^2}{n^2}
I assume that both are correct, but what makes the difference? Is it the same R for both of them? or the second R includes the h and c inside?
How would I tell the difference?

Please enlighten me. Thanks :)
 
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manenbu said:
I have a question which may seem stupid, but I think I missing something here.

I see 2 equations describing allowed energies for electrons in hydrogenic atoms, being:
E = -\frac{hcRZ^2}{n^2}
And
E = -\frac{RZ^2}{n^2}
I assume that both are correct, but what makes the difference? Is it the same R for both of them? or the second R includes the h and c inside?
How would I tell the difference?

Please enlighten me. Thanks :)

They are trying to express the same relation, and you are correct that in the second version, the h and c have been "absorbed" into the R. In the first case the dimension of R is 1/length, and R comes from the Rydberg formula for the wavelength of a photon coupling two H-atom energy levels. In the second case, the dimension of R is energy, and the R stands for the Rydberg unit of energy, which is defined as the ground state energy of the H-atom in the approximation of infinite nuclear mass. The atomic unit of energy, the hartree, is exactly two Rydbergs.
 
Ok, thank you.
It's just that some textbooks use either one, and none explain the difference.

Now I understand!
 

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