Another le chatelier qsneed to make sure

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Discussion Overview

The discussion revolves around the effects of adding dilute HCl to a K2CrO4 solution in the context of the equilibrium reaction involving chromate and dichromate ions. Participants explore the implications of Le Chatelier's principle on the equilibrium shift due to the addition of HCl, focusing on theoretical predictions and the behavior of the chemical species involved.

Discussion Character

  • Exploratory, Debate/contested, Conceptual clarification

Main Points Raised

  • One participant predicts that the reaction will shift to the right upon adding HCl, suggesting that the acid will donate protons that react with H+ to produce hydrogen gas.
  • Another participant challenges this by questioning the validity of the proton donation claim, indicating that H+ does not react with another H+ to form hydrogen gas.
  • A subsequent participant posits that the effect of HCl on the equilibrium may depend on its dilution relative to the concentrations of the reactants and products, suggesting that significant ionization of HCl could lead to a rightward shift in the reaction.

Areas of Agreement / Disagreement

Participants express differing views on the outcome of adding HCl, with no consensus reached on whether the reaction will shift or remain unchanged. The discussion reflects competing interpretations of the chemical behavior involved.

Contextual Notes

Participants note the importance of the concentration of HCl and its ionization in determining the reaction's response, highlighting potential dependencies on specific conditions that remain unresolved.

angel_eyez
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1. for the equilibrium reaction below predict what would happen if dilute HCl were added to the K2CrO4 solution?



2. 2CrO4(aq) + 2H+(aq) <--> Cr2O7(aq) + H2O



3. The reaction will shift to the right because the acid will donate a proton which will react with H+ to produce hydrogen gas so therefore the rxn has to shift to the right to use up HCl. i need to knwo if this is righhtt. THXN
 
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Try writing the equation for the ionization of HCl.

BTW, H+ will not donate a proton to another H+ to form hydrogen...

H+ + H+ -----> H2++ ? (won't happen)
 
So there will b no change in the equation??
 
I guess it depends on how dilute the HCl is compared to the concentrations of the reactants and products. If the HCl did contribute significantly, the HCl would ionize to produce more H+, so the reaction would shift to the right to counteract the addition of reactants.
 

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