Ans: Resonance Structures: Checking Answers Correctness

AI Thread Summary
The discussion focuses on verifying the correctness of answers related to resonance structures. Key points include the distinction between the inductive and mesomeric effects, with clarification that electron-donating groups like -OR are mesomerically electron donating, not attracting. Participants emphasize the importance of accurately drawing lone pairs and maintaining charge balance in resonance structures. The eighth question is debated, with consensus that it is correct but involves a conjugated pi bond with a lone pair rather than another pi bond. Overall, the conversation enhances understanding of resonance structures and the effects of various groups on electron movement.
chemJan2021
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Summary:: I would like to know if my answers of each resonance structure of the eight questions is correct or not.
I think the Inductive effect (induction) attracts electrons and affects up to three bonds as electron attracting group.
And the Mesomeric effect affects Pi- bonds as long as there are Pi-bonds.
And the Electron donating group (-NR2, -OR, -R) pull the electrons and the Electron attracting group (-NO2, -CO-, -COO-, -CN, -SO3R, halogen) attract the electrons.



 

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2 is right, the others are wrong (or 1 is incomplete). -OR is mesomerically electron donating, not attracting. Try drawing in all the lone pairs and counting electrons, and see why your suggested structures are wrong.
 
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Thank you for useful comments!
I really appreciate it! I’ll check and try drawing to get to know correct answers.
 
I rethink the answers of these seven questions of resonance structure (1, 3-8). I hope these are correct.
I think as there are only one Pi-bond in 1-7 questions, there is no mesomeric effect in these questions.
I couldn’t understand the answer of the eighth question is wrong. The answer of the eighth question is correct?
 

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They are all mesomeric; it's just that the pi bond is conjugated with a lone pair rather than another pi bond. 1-4 and 8 are correct. (In 8, the unconjugated pi bond is not involved in the resonance.) In 7 you have omitted the positive charge on the N. 5 and 6 are wrong - you are trying to move the pi bond to a saturated carbon. They are analogous to 3 and 4.
 
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Likes jim mcnamara, berkeman and chemJan2021
Thank you for your insightful comments!
I understand mesomeric effect in these resonance structure.
I understand the electrons of pi bond cannot be transferred to a saturated carbon and but to the next carbon of the pi bond. I think the electrons of pi bond can be transferred to a next cation of carbon but not to a saturated carbon.
I appreciate your quite useful teaching!
 

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These are now correct, except that there is a positive charge on the N in the RHS of 6. Remember to keep the total charge constant!
 
Thank you for your useful comment!
I’ll try to check to keep the total charge constant.
I put positive charge on the M in the RHS of no.6.
Your clear explanation helped me understand these resonance structures, thank you!
 
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