Are All Two-Particle Wave Functions Products of One-Particle Wave Functions?

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Discussion Overview

The discussion revolves around whether all two-particle wave functions can be expressed as products of one-particle wave functions. Participants explore the implications of this question in the context of quantum mechanics, particularly focusing on entangled states and the nature of correlations between particles.

Discussion Character

  • Debate/contested
  • Conceptual clarification
  • Mathematical reasoning

Main Points Raised

  • Some participants assert that not every two-particle wave function can be expressed as a product of two one-particle wave functions, citing examples such as entangled states.
  • One participant references Griffiths' textbook, which mentions entangled states that cannot be decomposed into products of one-particle wave functions.
  • Another participant provides the spin singlet state as an example of such an entangled state.
  • Some argue that if two particles are interacting, their wave function cannot be expressed as a product of single-particle functions, implying statistical correlation.
  • There is a discussion about the converse: whether statistically uncorrelated particles can be expressed as a direct product of their wave functions.
  • Participants clarify the definitions of statistical independence and correlation, discussing the implications for the representation of wave functions.
  • One participant suggests that interacting particles can still be represented as a linear expansion of single-particle functions, although this is presented as a more complex scenario.
  • There is a correction regarding the notation of probability expressions, emphasizing the importance of precise definitions in the context of the discussion.

Areas of Agreement / Disagreement

Participants do not reach a consensus; multiple competing views remain regarding the nature of two-particle wave functions and their relationship to one-particle wave functions, particularly in the context of entanglement and statistical independence.

Contextual Notes

Limitations include the dependence on definitions of entanglement and statistical independence, as well as the unresolved mathematical steps regarding the representation of wave functions in different contexts.

majed_q8i
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Ever two-particle wave function is a product of two one-particle wave functions.
Is this true?
if not, can you give me a example ?
Thank you :)
 
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You can have [tex]\psi(x_1,x_2)[/tex] that does not equal
[tex]\phi_1(x_1)\phi_2(x_2)[/tex],
or you can have a wave function that is a sum of products.
 
in griffiths, 2nd edition, page 203
says that there exist entangled states that cannot be decomposed to the product of two one-particle wave function.

can you describe entangled states of this type?
I mean write down the equation.


Thanks!
 
An example, as stated in that same page in Griffiths is the spin singlet state |ud - du>. See pgs 184-185.
 
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majed_q8i said:
Ever two-particle wave function is a product of two one-particle wave functions.
Is this true?
if not, can you give me a example ?
Thank you :)

If that were true, then any function in 2 variables can be decomposed as a product of two functions in one variable.

But such a function would have the property that it has no zeroes, or infinitely many zeroes, since if h(x0,y0)= f(x0)g(y0)=0, then either f(x0)=0 or g(y0)=0, which implies h(x0,y) and h(x,y0) are zero for all y and x, respectively.
 
majed_q8i said:
Ever two-particle wave function is a product of two one-particle wave functions. Is this true? if not, can you give me a example ?

It's not true any time those two particles are interacting. If your wave function is a product of two single-particle functions, then every observable quantity is a product of the probabilities for the respective particles. I.e. they're statistically uncorrelated and so, independent of each other.
 
alxm said:
It's not true any time those two particles are interacting. If your wave function is a product of two single-particle functions, then every observable quantity is a product of the probabilities for the respective particles. I.e. they're statistically uncorrelated and so, independent of each other.

Is the converse true? That is, if they're statistically uncorrelated, can they be written as a direct product?
 
RedX said:
Is the converse true? That is, if they're statistically uncorrelated, can they be written as a direct product?

Statistical non-correlation means that P(A|B) = P(A)P(B), so yes.

I might want to add to the earlier that any set of interacting (correlated) particles may still be written as a linear expansion of different single-particle functions though. (Handwaving: Throw out the interaction terms from the Hamiltonian and solve for the single particles which can be used as a basis for the interacting Hamiltonian. E.g. a Slater determinant)
 
  • #10
alxm said:
Statistical non-correlation means that P(A|B) = P(A)P(B), so yes.

I might want to add to the earlier that any set of interacting (correlated) particles may still be written as a linear expansion of different single-particle functions though. (Handwaving: Throw out the interaction terms from the Hamiltonian and solve for the single particles which can be used as a basis for the interacting Hamiltonian. E.g. a Slater determinant)

oh yes, that is almost by definition. If you have P(x,y), and P(x|y=a)=P(x,a)=f(x)g(a), then it must be true that P(x,y)=f(x)g(y), or that the state can be written:

[tex]|\psi>=|\sqrt{f}>\otimes|\sqrt{g}>[/tex]
 
  • #11
oh, I think you and I made a slight error. It's not:

P(A|B) = P(A)P(B)

but

[tex]P(A \cap B)=P(A)P(B)[/tex]

If you wanted to use conditional probability, then the equation would be:

P(A|B) = P(A)

Anyways, I don't think this changes the concept, just the notation:

[tex]P( (x=a) \cap (y=b))=P(a,b)=f(a)g(b)[/tex], then it must be true that P(x,y)=f(x)g(y), or that the state can be written:

[tex] |\psi>=|\sqrt{f}>\otimes|\sqrt{g}> [/tex]

Where here the x,y, positions are uncorrelated, and:


[tex] (<x|\otimes <y|)|\psi>=\sqrt{f(x)} \sqrt{g(y)} [/tex]

addendum

I guess technically one should show that if [tex]\psi(x,y)[/tex] can't be written as a direct product, i.e., [tex]\psi(x,y)\neq f(x)g(y)[/tex], then it's modulus squared can't be written as one either. But that's easy, since if it's modulus squared could be written as one, then just by taking the square root contradicts that [tex]\psi(x,y)[/tex] can't be written as a direct product.
 
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