The coordinate operator in quantum mechanics is considered Hermitian because it operates on real-valued coordinates, particularly in the context of a one-dimensional free particle. In the Schrödinger picture, the coordinate operator is directly linked to the canonical commutation relation [x,p] = ihbar, and it can be shown to be self-adjoint on its maximal domain. However, the coordinate operator is not a simple matrix; it necessitates the use of Rigged Hilbert Spaces and the Generalized Spectral Theorem for a comprehensive understanding. This rigorous treatment is complex and requires a solid mathematical foundation. Resources like Ballentine and Hall's "Quantum Theory For Mathematicians" are recommended for those looking to deepen their understanding.