Atomic Spectra, transmission of photons

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Homework Help Overview

The discussion revolves around the calculation of the wavelength of photons emitted during a rotational transition of the H_2 molecule, utilizing concepts from angular momentum and the Bohr model. The problem involves quantized angular momentum and the relationship between rotational energy and wavelength.

Discussion Character

  • Exploratory, Assumption checking, Mathematical reasoning

Approaches and Questions Raised

  • Participants discuss the application of the rotational energy formula and the quantization of angular momentum. There are questions about the appropriateness of using the Bohr model in conjunction with the provided energy equation. Some participants express uncertainty regarding the calculations and the significance of the squared term in the energy formula.

Discussion Status

There is an ongoing exploration of the calculations, with participants suggesting that the original poster revisit their numerical inputs. Some have noted improvements in their results after correcting errors, but there is still a lack of consensus on the final wavelength value and its implications.

Contextual Notes

Participants mention the context of molecular transitions and the expected order of magnitude for wavelengths, indicating a distinction between molecular and atomic transitions. There is also a recognition of the potential discrepancies in energy calculations based on the assumptions made.

Brewer
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Homework Statement


A molecule with angular momentum L and moment of inertia I has a rotational energy that can be written as E=\frac{L^2}{2I}. Assuming that angular momentum is quantized according to Bohr's rule L = n\hbar, find the wavelength of the photons emitted in the n=2 to n=1 tranistion of the H_2 molecule. This molecule has moment of inertia I = \frac{1}{2}mr_0^2, where m=938MeV/c^2 and r_0 = 0.074nm.


Homework Equations


I assumed only the ones given in the question.
Possibly the Bohr Model


The Attempt at a Solution


By using the rotational energy alone as given above I got a \delta E = 2.30x{tex]10^{13}[/tex] J, which in turn lead to an emitted wavelength of something of the order 48. I can see that this is clearly wrong.

Do I need to use the Bohr model equation for this as well somehow? The rotational energy given by the numbers in the question is tiny, thus giving a huge rotational energy. But the energies given from the Bohr model are quite small, so simple addition of them is pointless, as the Bohr model won't have much (if any) effect on the overall energy will it?
 
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It looks like you have everything you need. Your energy is clearly way off. I would suggest you put the numbers back in again - or show some intermediate steps.
 
Looks like I forgot the squared term in the numerator of the fraction.

When I remember this, it looks like the wavelength I come out with is of the order 10^{-5}. This looks better doesn't it?
 
Brewer said:
Looks like I forgot the squared term in the numerator of the fraction.

When I remember this, it looks like the wavelength I come out with is of the order 10^{-5}. This looks better doesn't it?
No idea abt molecules but for Bohr species its generally of the order10^{-7} m
 
Brewer said:
Looks like I forgot the squared term in the numerator of the fraction.

When I remember this, it looks like the wavelength I come out with is of the order 10^{-5}. This looks better doesn't it?

This is a molecular rotational transition, much longer wavelength than Bohr. 10^(-5) is about right.
 

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