Balancing a Redox Equation with Half-Reactions

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Discussion Overview

The discussion focuses on balancing a redox equation involving sulfur dioxide and potassium dichromate in an acidic solution. Participants explore the half-reaction method to achieve balance while addressing the role of potassium ions and sulfate species.

Discussion Character

  • Technical explanation
  • Mathematical reasoning
  • Debate/contested

Main Points Raised

  • One participant presents an initial equation and expresses uncertainty about how to balance it, particularly regarding the potassium ion.
  • Another participant suggests that the potassium ion is a spectator and that sulfur trioxide in water leads to sulfate ions.
  • A participant acknowledges the hint about the potassium ion and proposes a revised equation, attempting to balance the half-reactions while questioning the correctness of their approach.
  • A later reply indicates that the revised balancing looks acceptable to them, but does not provide a definitive confirmation.

Areas of Agreement / Disagreement

Participants do not reach a consensus on the final correctness of the balanced equation, as one participant expresses uncertainty about their solution while another tentatively agrees with it.

Contextual Notes

There are unresolved aspects regarding the treatment of potassium ions and the transition from sulfur trioxide to sulfate ions, which may affect the overall balancing of the equation.

RaamGeneral
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It's not clear to me how I can balance the following equation, most of all because of K which I don't know how to deal with:

\mathrm{SO_2 + K_2Cr_2O_7 \to Cr_2(SO_4)_3 + SO_3} [this is the text of the exercise]

It's acidic solution for sulfuric acid, so the equation can be better written so:

\mathrm{SO_2 + K_2Cr_2O_7 + H_2SO_4 \to Cr_2(SO_4)_3 + SO_3 + H_2O + K} (I assume K has to be added, preserving the charge in both members)

To use the half-reaction method I write the ionic form:

\mathrm{SO_2+K^+ + Cr_2O_7^{2-}+H^+ \to Cr^{3+}+SO_3+H_2O + K}

Writing and balancing three half-reactions (can it be?) I get:

\mathrm{4SO_2 + K_2Cr_2O_7+3H_2SO_4 \to 4SO_3 + Cr_2(SO_4)_3+2K+3H_2O}Is it correct?

Thank you.
 
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Hint: K+ is just a spectator, and SO3 in water means just SO42-.
 
Ok, your hint was foundamental to me.
I have already thought about K+ being spectator but I "forgot" that
\mathrm{ SO_3 + H_2O\to H_2SO_4\to 2H^+ + SO_4^{2-} } (right?) so I didn't know what to do without K in the second member.\mathrm{SO_2 + K_2Cr_2O_7 + H_2SO_4\to Cr_2(SO_4)_3 + SO_3 + H_2O + 2K^+ }
\mathrm{SO_2 + K_2Cr_2O_7 \to Cr_2(SO_4)_3 + 2K^+ }
ionic form: \mathrm{SO_2 + Cr_2O_7^{2-}\to Cr^{3+} + SO_4^{2-} }

Balancing the two half-reactions:

\mathrm{3SO_2 + Cr_2O_7^{2-} + 2H^+\to 3SO_4^{2-} + 2Cr^{3+} + H_2O }

And finally:

\mathrm{3SO_2 + K_2Cr_2O_7 + H_2SO_4\to K_2SO_4 +Cr_2(SO_4)_3 + H_2O }I'm not so sure though. Is it correct?

Thank you for your reply.
 
Last edited:
Looks OK to me.
 

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