Balancing Net Ionic Equation: MnO4- + HSO3- in Acidic Solution

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To balance the net ionic equation for the reaction between MnO4- and HSO3- in an acidic solution, one must recognize it as a redox reaction involving an oxidizing agent (MnO4-) and a reducing agent (HSO3-). The key is to identify the appropriate half-cell reactions by consulting a table of redox potentials, focusing on the manganese species transitioning to MnO or MnO2. The bisulfite ion requires careful selection of half-reactions to balance with the reactants, ensuring favorable redox potentials. Understanding the specific conditions under which the reaction occurs is also crucial for accurate balancing. This approach will lead to the correct balanced net ionic equation.
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Homework Statement



Balance the net ionic equation:

Acidic: MnO4-(aq) + HSO3-(aq) =

The Attempt at a Solution



I honestly don't know where to start, and I can't find anything similar in the book. I just need a push in the right direction
 
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That appears to be either an oxidizing agent with a reducing agent; or maybe but not likely, a weak acid and the anion of another weak acid for some neutralization. What are you really hoping to try?
 
It's redox. I just don't know how to find the products
 
You could choose the best half-cell reactions by inspecting a table of redox potentials. I believe you only are concerned with the Mn part going to MnO or MnO2. For the bisulfite, you'll need to choose from various half-reactions balancing each of them with the reactants which you were given and find which one or which ones give favorable redox potentials in the balanced equation. Also helpful would be to know what kind of conditions your reaction would be occurring.
 

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