Boron esters and oxygen removal

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SUMMARY

The discussion focuses on the removal of oxygen from boron powders through milling in methanol, which facilitates the formation of boron esters, specifically trimethyl borate. It is established that B2O3 reacts with methanol, producing boron esters that volatilize during solvent evaporation under reduced pressure. However, the formation of these esters is significantly enhanced in the presence of an acid catalyst, such as sulfuric acid. The boiling point of trimethyl borate is noted as 69°C at atmospheric pressure.

PREREQUISITES
  • Understanding of boron oxide (B2O3) chemistry
  • Familiarity with milling techniques and solvent use
  • Knowledge of esterification reactions and catalysts
  • Basic principles of vacuum evaporation processes
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  • Research the process of milling boron powders in methanol
  • Study the role of sulfuric acid as a catalyst in esterification
  • Learn about the properties and applications of trimethyl borate
  • Explore vacuum evaporation techniques for solvent removal
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Chemists, materials scientists, and researchers involved in boron chemistry and ester synthesis will benefit from this discussion.

woodyanderson
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I would like to remove oxygen from boron powers by milling in milling the starting powders in an alcohol, specifically, methanol. I've been told B2O3 reacts with the methanol to produce boron esters which volatilise during evaporation of the milling solvent under a reduced pressure. Is this true?
How can this be done
 
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Take a look at this thread: https://www.physicsforums.com/showthread.php?t=93439

Although in your case your dealing with boron oxide, I do not think that the mechanism would be much different. You should not get much ester formation without an acid catalyst like sulfuric acid. The primary ester in question is trimethyl borate which boils at 69C at atmospheric pressure.
 
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