Calculating electronegativity differences

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To calculate the electronegativity difference for sodium oxide (Na2O), the correct formula is ΔX_Na2O = X_O - X_Na. The alternative suggestion of ΔX_Na2O = X_O - 2*X_Na is incorrect, as the electronegativity difference is determined by the individual atoms involved in the bond, not the number of atoms. This difference is primarily used to assess the polarity of the bond between the two elements.
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Hi, everyone!

Just a quick question to be sure:

I want to calculate the electronegativity difference of Na_{2}O,\ \Delta X_{Na_{2}O},

Is this correct:

\Delta X_{Na_{2}O}=X_{O}-X_{Na}

Or is it:

\Delta X_{Na_{2}O}=X_{O}-2*X_{Na} (since there are 2 Na atoms).
 
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The first alternative without the factor 2 is correct. Usually, you use the electronegativity difference to estimate the polarity of a bond between two atoms. Other atoms bonded to these atoms are not relevant.
 
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Thank you very much for your quick reply, DrDu!
 
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